| Identification | Back Directory | [Name]
2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine | [CAS]
1660153-91-2 | [Synonyms]
2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98%
2-(t-Butylphenylphosphino)-2',6'-dimethylamino-1,1'-biphenyl, 98% (t-Bu)PhCPhos
2'-[(1,1-Dimethylethyl)phenylphosphino]-N2,N2,N6,N6-tetramethyl-[1,1'-biphenyl]-2,6-diamine | [Molecular Formula]
C26H33N2P | [MDL Number]
MFCD29905429 | [MOL File]
1660153-91-2.mol | [Molecular Weight]
404.53 |
| Chemical Properties | Back Directory | [Melting point ]
112 °C | [Boiling point ]
537.6±50.0 °C(Predicted) | [form ]
Powder | [pka]
5.00±0.28(Predicted) | [color ]
white to off-white | [InChI]
InChI=1S/C26H33N2P/c1-26(2,3)29(20-14-9-8-10-15-20)24-19-12-11-16-21(24)25-22(27(4)5)17-13-18-23(25)28(6)7/h8-19H,1-7H3 | [InChIKey]
HTHOMNNVAUPLKK-UHFFFAOYSA-N | [SMILES]
C1(C2=CC=CC=C2P(C(C)(C)C)C2=CC=CC=C2)=C(N(C)C)C=CC=C1N(C)C |
| Hazard Information | Back Directory | [Uses]
(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines. | [reaction suitability]
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand |
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