| Identification | More | [Name]
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL | [CAS]
16854-32-3 | [Synonyms]
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
(1S,2S)-(+)-THIOMICAMINE
L-THIOMICAMINE
2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol
[S(R*,R*)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol
thiomicamine
(1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol
(1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol | [EINECS(EC#)]
240-878-4 | [Molecular Formula]
C10H15NO2S | [MDL Number]
MFCD00134212 | [Molecular Weight]
213.3 | [MOL File]
16854-32-3.mol |
| Chemical Properties | Back Directory | [Melting point ]
151-154 °C(lit.) | [Boiling point ]
428.2±45.0 °C(Predicted) | [density ]
1.25±0.1 g/cm3(Predicted) | [storage temp. ]
2-8°C, stored under nitrogen | [pka]
11.75±0.45(Predicted) | [Appearance]
White to off-white Powder | [Optical Rotation]
[α]25/D +25°, c = 1 in ethanol | [InChI]
1S/C10H15NO2S/c1-14-8-4-2-7(3-5-8)10(13)9(11)6-12/h2-5,9-10,12-13H,6,11H2,1H3/t9-,10-/m0/s1 | [InChIKey]
IULJJGJXIGQINK-UWVGGRQHSA-N | [SMILES]
CSc1ccc(cc1)[C@H](O)[C@@H](N)CO | [CAS DataBase Reference]
16854-32-3(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
2930909899 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
(1S,2S)-(+)-Thiomicamine can be used:
- As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.
- As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
- As a chiral base in the resolution of an angiotensin II type 2 receptor [AT2R] antagonist named EMA401.
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Energy Chemical
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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Merck KGaA
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www.sigmaaldrich.cn |
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