ChemicalBook--->CAS DataBase List--->16881-77-9

16881-77-9

16881-77-9 Structure

16881-77-9 Structure
IdentificationMore
[Name]

Methyldimethoxysilane
[CAS]

16881-77-9
[Synonyms]

DIMETHOXY(METHYL)SILANE
METHYLDIMETHOXYSILANE
dimethoxymethyl-silan
Dimethoxymethylsilane. Methylhydrogendimethoxysilane.
Dimethoxy(methyl)silicon
[EINECS(EC#)]

240-914-9
[Molecular Formula]

C3H10O2Si
[MDL Number]

MFCD00048019
[Molecular Weight]

106.2
[MOL File]

16881-77-9.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless clear liquid
[Melting point ]

-136°C
[Boiling point ]

61 °C
[density ]

0.861
[vapor pressure ]

0.05-12790Pa at 20-25℃
[refractive index ]

1.3600
[Fp ]

<0°C
[storage temp. ]

Storage temp. 2-8°C
[solubility ]

Chloroform (Sparingly), Ethyl Acetate (Slightly)
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

0.861
[Water Solubility ]

17-1000g/L at 20℃
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[BRN ]

2035898
[LogP]

-2.4-1.4
[CAS DataBase Reference]

16881-77-9(CAS DataBase Reference)
[EPA Substance Registry System]

16881-77-9(EPA Substance)
Questions And AnswerBack Directory
[Preparation]

Under certain temperature, catalyst, and initiator conditions, 1,3,5,7-tetramethylcyclotetrasiloxane and trimethyl orthoformate are reacted via chain cleavage and transesterification to yield methyldimethoxysilane. A stabilizer is added during the reaction to suppress the disproportionation reaction.
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)Exclamation Mark (GHS07)
GHS02,GHS05,GHS06,GHS07
[Signal word ]

Danger
[Hazard statements ]

H225-H311-H315-H318-H335
[Precautionary statements ]

P210-P233-P240-P241+P242+P243-P264-P280-P302+P352+P312+P361+P364-P305+P351+P338+P310-P370+P378-P403+P235-P405-P501-P261-P303+P361+P353-P305+P351+P338-P501a
[Risk Statements ]

R11:Highly Flammable.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

1992
[RTECS ]

VV3644166
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29319090
[Safety Profile]

A poison by ingestion, subcutaneous, and intravenous routes. A moderate eye irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2,4,6,8-Tetramethylcyclotetrasiloxane-->Trimethoxymethane
[Preparation Products]

3-Methacryloxypropylmethyldimethoxysilane-->3-(Dimethoxymethylsilyl)propylamine-->Cyclohexyldimethoxymethylsilane-->2-(3,4-Epoxycyclohexyl) ethylmethyl dimethoxysilane
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Methyldimethoxysilane(16881-77-9).msds
Hazard InformationBack Directory
[Hazard]

A poison by ingestion. A moderate eye irri-tant.
[Description]

Methyldimethoxysilane, reactive silane containing both Si-H and methoxy functional groups. The SiH group can be utilized for hydrosilylation to form methoxysilyl functional materials. Modification by hydrosilylation can bring the benefit of moisture cure or crosslinking by reactive methoxy groups.
[Chemical Properties]

Colorless clear liquid
[Uses]

Modifications by hydrosilylation reaction.
[Flammability and Explosibility]

Highlyflammable
[Toxics Screening Level]

The ITSL for methyldimethoxysilane is 92 μg/m3 based on an annual averaging time.
Spectrum DetailBack Directory
[Spectrum Detail]

Methyldimethoxysilane(16881-77-9)MS
Methyldimethoxysilane(16881-77-9)1HNMR
Methyldimethoxysilane(16881-77-9)13CNMR
Methyldimethoxysilane(16881-77-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Dimethoxymethylsilane, 97%(16881-77-9)
[TCI AMERICA]

Dimethoxy(methyl)silane,>97.0%(GC)(16881-77-9)
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