ChemicalBook--->CAS DataBase List--->1754-49-0

1754-49-0

1754-49-0 Structure

1754-49-0 Structure
IdentificationMore
[Name]

DIETHYL PHENYLPHOSPHONATE
[CAS]

1754-49-0
[Synonyms]

AURORA KA-1484
BENZENEPHOSPHONIC ACID DIETHYL ESTER
DIETHYL BENZENEPHOSPHONATE
DIETHYL PHENYLPHOSPHONATE
PHENYLPHOSPHONIC ACID DIETHYL ESTER
phenyl-phosphonicacidiethylester
Diethoxyphosphinylbenzene
Phenylphosphonic acid diethyl
TA03770000
[EINECS(EC#)]

217-129-5
[Molecular Formula]

C10H15O3P
[MDL Number]

MFCD00015136
[Molecular Weight]

214.2
[MOL File]

1754-49-0.mol
Chemical PropertiesBack Directory
[Boiling point ]

110-112°C 1mm
[density ]

1,12 g/cm3
[refractive index ]

1.4940
[Fp ]

267°C
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Water Solubility ]

<0.2g/L(25 ºC)
[BRN ]

2449931
[CAS DataBase Reference]

1754-49-0(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Danger
[Hazard statements ]

H302
[Precautionary statements ]

P264-P270-P301+P312a-P330-P501a
[Risk Statements ]

R22:Harmful if swallowed.
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

2810
[RTECS ]

TA0377000
[PackingGroup ]

III
[HS Code ]

29319090
[Toxicity]

mouse,LD50,intraperitoneal,790mg/kg (790mg/kg),Farmakologiya i Toksikologiya Vol. 10, Pg. 121, 1975.
Hazard InformationBack Directory
[Uses]

Diethyl phenylphosphonate is a liquid that can be used as an organophosphine ligand in organic synthesis.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 69, p. 2020, 1947 DOI: 10.1021/ja01200a059
The Journal of Organic Chemistry, 39, p. 3612, 1974 DOI: 10.1021/jo00938a045
[Synthesis]

A dried 25 mL flask was charge with triethyl phosphite (11.0 mmol, 1.27 mL) and benzoyl chloride (10.0 mmol, 1.72 mL). After the mixture was stirred for 12 h at room temperature, the crude product was purified by column chromatography over silica gel (300–400 mesh) using CH2Cl2 as an eluent to give analytically pure product Diethyl Phenylphosphonate.
Spectrum DetailBack Directory
[Spectrum Detail]

DIETHYL PHENYLPHOSPHONATE(1754-49-0)MS
DIETHYL PHENYLPHOSPHONATE(1754-49-0)1HNMR
DIETHYL PHENYLPHOSPHONATE(1754-49-0)13CNMR
DIETHYL PHENYLPHOSPHONATE(1754-49-0)IR1
DIETHYL PHENYLPHOSPHONATE(1754-49-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Diethyl phenylphosphonate, 97%(1754-49-0)
[TCI AMERICA]

Diethyl Phenylphosphonate,>96.0%(GC)(1754-49-0)
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