ChemicalBook--->CAS DataBase List--->17577-28-5

17577-28-5

17577-28-5 Structure

17577-28-5 Structure
IdentificationMore
[Name]

(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
[CAS]

17577-28-5
[Synonyms]

(4-ETHOXYCARBONYL)TRIPHENYLPHOSPHONIUM CHLORIDE
CARBETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE
(CARBOETHOXYMETHYL)-TRIPHENYLPHOSPHONIUMCHLORID
(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE
(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE
(2-ethoxy-2-oxoethyl)triphenylphosphonium chloride
(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONI UM CHLORIDE, TECH., 80%
(ETHOXYCARBONYLMETHYL)TRIPHENYL PHOSPHO&
ethyl (triphenylphosphonio)acetate chloride
(ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE 97%
[(Ethoxycarbonyl)methyl]triphenylphosphonium chloride, 97 %
[EINECS(EC#)]

241-548-2
[Molecular Formula]

C22H24ClO3P
[MDL Number]

MFCD03791276
[Molecular Weight]

402.85
[MOL File]

17577-28-5.mol
Chemical PropertiesBack Directory
[Appearance]

white to off-white crystals or crystalline powder
[Melting point ]

120-123 °C (dec.) 120-123 °C (lit.)
[storage temp. ]

2-8°C
[Sensitive ]

Hygroscopic
[BRN ]

3924139
[InChI]

1S/C22H22O2P.ClH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
[InChIKey]

DJGHVEPNEJKZBF-UHFFFAOYSA-M
[SMILES]

[Cl-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
[CAS DataBase Reference]

17577-28-5(CAS DataBase Reference)
[EPA Substance Registry System]

Phosphonium, (2-ethoxy-2-oxoethyl)triphenyl-, chloride (17577-28-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[F ]

9
[TSCA ]

Yes
[HS Code ]

29319019
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

white to off-white crystals or crystalline powder
[Uses]

Reactant for:
  • Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
  • Ring-opening reactions with Wittig reagents
  • Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
  • Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
  • Preparation of phosphonium derivatives of coumarin
[reaction suitability]

reaction type: C-C Bond Formation
Spectrum DetailBack Directory
[Spectrum Detail]

(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE(17577-28-5)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(Carboethoxymethyl)triphenylphosphonium chloride hydrate, 97%(17577-28-5)
[Alfa Aesar]

(Ethoxycarbonylmethyl)triphenylphosphonium chloride, 97%(17577-28-5)
[Sigma Aldrich]

17577-28-5(sigmaaldrich)
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17577-28-5 35000-37-4 1031-15-8 896-33-3