ChemicalBook--->CAS DataBase List--->18171-11-4

18171-11-4

18171-11-4 Structure

18171-11-4 Structure
IdentificationMore
[Name]

CHLOROMETHYLDIMETHYLISOPROPOXYSILANE
[CAS]

18171-11-4
[Synonyms]

CHLOROMETHYLDIMETHYLISOPROPOXYSILANE
(Chloromethyl)-isopropoxy-dimethylsilane
CHLOROMETHYLDIMETHYLISOPROPOXYSILANE, 97 %
chloromethyldimethylisopropoxysilane96+%
CHLOROMETHYLDIMETHYLISOPROPOXYSILANE 97%
(Isopropoxydimethylsilyl)methyl chloride
[EINECS(EC#)]

200-258-5
[Molecular Formula]

C6H15ClOSi
[MDL Number]

MFCD00010605
[Molecular Weight]

166.72
[MOL File]

18171-11-4.mol
Chemical PropertiesBack Directory
[Boiling point ]

64-66 °C/54 mmHg (lit.)
[density ]

0.926 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.415(lit.)
[Fp ]

83 °F
[form ]

clear liquid
[color ]

Colorless to Light yellow
[Specific Gravity]

0.947
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[BRN ]

1736255
[InChI]

InChI=1S/C6H15ClOSi/c1-6(2)8-9(3,4)5-7/h6H,5H2,1-4H3
[InChIKey]

KOTFCAKXPLOYLN-UHFFFAOYSA-N
[SMILES]

[Si](CCl)(C)(C)OC(C)C
[CAS DataBase Reference]

18171-11-4(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Warning
[Hazard statements ]

H226-H315-H319-H335
[Precautionary statements ]

P210-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[F ]

21
[TSCA ]

No
[REACH Registrations]

Active
[HazardClass ]

3.2
[PackingGroup ]

III
[HS Code ]

29319090
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Used as the Grignard reagent is a nucleophilic hydroxymethylating agent for aldehydes, ketones, epoxides, organic halides, and sulfoximines.
[storage]

moisture sensitive, but no special precautions are necessary for  handling in the air for a short period of time. May be stored under nitrogen in a tightly capped bottle in a  refrigerator.
Spectrum DetailBack Directory
[Spectrum Detail]

CHLOROMETHYLDIMETHYLISOPROPOXYSILANE(18171-11-4)1HNMR
CHLOROMETHYLDIMETHYLISOPROPOXYSILANE(18171-11-4)Raman
CHLOROMETHYLDIMETHYLISOPROPOXYSILANE(18171-11-4)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

18171-11-4(sigmaaldrich)
[TCI AMERICA]

(Chloromethyl)dimethylisopropoxysilane,>96.0%(GC)(18171-11-4)
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