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1822-00-0

1822-00-0 Structure

1822-00-0 Structure
IdentificationBack Directory
[Name]

(TRIMETHYLSILYL)METHYLLITHIUM
[CAS]

1822-00-0
[Synonyms]

Lithiomethyltrimethylsilane
RIMETHYLSILYL)METHYLLITHIUM
Trimethylsiloxy-Methyllithium
Trimethyl(lithiomethyl)silane
Lithio(trimethylsilyl)methane
(TRIMETHYLSILYL)METHYLLITHIUM
Lithium, (trimethylsilyl)methyl-
lithium,methanidyl(trimethyl)silane
(trimethylsilyl)methyllithiumsolution
TRIMETHYLSILYLMETHYLLITHIUM, 1M in hexane
lithium(1+) ion (trimethylsilyl)methanide
((trimethylsilyl)methyl)lithium 1.0M in pentane
(TriMethylsilyl)MethyllithiuM solution in Hexane
(TRIMETHYLSILYL)METHYLLITHIUM ISO 9001:2015 REACH
trimethylsilylmethyllithium, 1m in hexane (13-14 wt %)
(TRIMETHYLSILYL)METHYLLITHIUM SOLUTION, ~1 M IN PENTANE
(TriMethylsilyl)MethyllithiuM solution 1.0 M in pentane
(TRIMETHYLSILYLMETHYL)LITHIUM , 1.0M SOL UTION IN PENTANE
(Trimethylsilyl)methyllithium,0.8M (12 wt%) solution in hexanes
(TriMethylsilyl) MethyllithiuM, 1.0 M solution in pentane, SpcSeal
(Trimethylsilyl)methyllithium, 0.55 M solution in hexanes, J&KSeal
(TriMethylsilyl) MethyllithiuM, 0.56 M solution in hexanes, SpcSeal
(Trimethylsilyl)methyllithium, 0.8M (12 wt%) solution in hexanes, AcroSeal
(TriMethylsilyl)MethyllithiuM, 0.7M (10 wt%) solution in hexanes, AcroSeal
(Trimethylsilyl)methyllithium, 0.8M (12 wt%) solution in hexanes, AcroSeal§3
[Molecular Formula]

C4H11LiSi
[MDL Number]

MFCD00010747
[MOL File]

1822-00-0.mol
[Molecular Weight]

94.16
Chemical PropertiesBack Directory
[Melting point ]

112-117 °C (decomp)
[Boiling point ]

35-36 °C
[density ]

0.65 g/mL at 25 °C
[Fp ]

−57 °F
[storage temp. ]

2-8°C
[solubility ]

Sol ethereal solvents; reacts with protic solvents.
[Specific Gravity]

0.66
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[BRN ]

4123225
[InChI]

InChI=1S/C4H11Si.Li/c1-5(2,3)4;/h1H2,2-4H3;
[InChIKey]

RJPBNMJOQNIBQW-UHFFFAOYSA-N
[SMILES]

[Si](C)(C)(C)C[Li]
Safety DataBack Directory
[Hazard Codes ]

F,C,N,F+
[Risk Statements ]

11-14-34-51/53-65-66-67-12-2
[Safety Statements ]

16-26-33-36/37/39-43-45-61-62
[RIDADR ]

UN 3399 4.3/PG 1
[WGK Germany ]

1
[F ]

10
[REACH Registrations]

Active
[HazardClass ]

4.2
[PackingGroup ]

I
[HS Code ]

29319090
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Aquatic Chronic 2
Asp. Tox. 1
Eye Dam. 1
Flam. Liq. 1
Skin Corr. 1B
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

Clear light yellow liquid
[Physical properties]

mp 112 °C.
[Uses]

Initiates polymerization and copolymerization of cyclosiloxanes.1 Alkylates metal complexes.2
[Preparation]

Trimethylsilylmethyllithium is obtained by reaction of (chloromethyl)- trimethylsilane with lithium metal in an inert solvent. It is also available by displacement of a heteroatom group based on sulfur, silicon, or tin.
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