| Identification | Back Directory | [Name]
4-THIOANISOLEMAGNESIUM BROMIDE | [CAS]
18620-04-7 | [Synonyms]
emag
4-ThioanisoL
emagnesium bromide
4-THIOANISOLEMAGNESIUM BROMIDE
4-(Methylthio)phenylmagnesium bromide
p-(Methylthio)phenylmagnesium bromide
Magnesium,bromo[4-(methylthio)phenyl]-
magnesium,methylsulfanylbenzene,bromide
4-thioanisolemagnesium bromide solution
4-Thioanisolemagnesium bromide,0.5M solutionin THF
4-Thioanisolemagnesium bromide solution 0.5M in THF
4-(Methylsulfanyl)phenylmagnesium bromidee, 0.5 M in THF
4-ThioanisoleMagnesiuM broMide, 0.5 M solution in THF, SpcSeal
4-ThioanisoleMagnesiuM broMide, 0.5 M solution in THF, J&KSeal
4-Thioanisolemagnesium bromide, 0.5M solution in THF, AcroSeal
4-THIOANISOLEMAGNESIUM BROMIDE, 0.5M SOLUT TION IN TETRAHYDROFURAN
4-Thioanisolemagnesium bromide, 0.5M solution in THF, AcroSeal&trade | [Molecular Formula]
C7H7BrMgS | [MDL Number]
MFCD00672010 | [MOL File]
18620-04-7.mol | [Molecular Weight]
227.4 |
| Chemical Properties | Back Directory | [Boiling point ]
65 °C
| [density ]
0.965 g/mL at 25 °C
| [Fp ]
<1 °F
| [storage temp. ]
2-8°C | [form ]
Solution | [color ]
Clear yellow to brown | [InChI]
1S/C7H7S.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1 | [InChIKey]
SSVQCUSLJVVRCA-UHFFFAOYSA-M | [SMILES]
CSc1ccc([Mg]Br)cc1 |
| Hazard Information | Back Directory | [Chemical Properties]
Tan liquid | [Uses]
4-Thioanisolemagnesium bromide can be used to prepare:
- 3,3-Ethylenedioxy-5a-hydroxy-11b-[4-(thiomethoxy)phenyl]-estr-9-en-17-one, a key intermediate for the synthesis of mifepristone analogs.
- (1S)-1,4-Anhydro-2,3,5,6-tetra-O-benzyl-1-C-[4-chloro-3-(4-methylthiobenzyl)-phenyl]-D-glucitol, a key intermediate for the synthesis of aryl?D-glucofuranosides as potent hSGLT2 and hSGLT1 inhibitors.
| [reaction suitability]
reaction type: Grignard Reaction |
|
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Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
| Company Name: |
3A Chemicals
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400-668-9898 |
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www.3achem.com |
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