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1875-48-5

1875-48-5 Structure

1875-48-5 Structure
IdentificationMore
[Name]

N-AMINOPHTHALIMIDE
[CAS]

1875-48-5
[Synonyms]

2-AMINOISOINDOLINE-1,3-DIONE
N-AMINOPHTHALIMIDE
N,N-PHTHALOYLHYDRAZINE, UNSYM
SPECS AQ-344/40414632
Aminophthalimidetech
N-AMINOPHTHALIMIDE, TECH., 90%
N-Aminophthalimide, 90%, tech.
2-Amino-2H-isoindole-1,3-dione
Phthalimidylamine
[EINECS(EC#)]

217-505-9
[Molecular Formula]

C8H6N2O2
[MDL Number]

MFCD00005895
[Molecular Weight]

162.15
[MOL File]

1875-48-5.mol
Chemical PropertiesBack Directory
[Appearance]

white to off-white crystalline powder
[Melting point ]

200-202 °C(lit.)
[Boiling point ]

288.82°C (rough estimate)
[density ]

1.3264 (rough estimate)
[refractive index ]

1.5770 (estimate)
[storage temp. ]

2-8°C
[solubility ]

Solubility in hot methanol almost transparent.
[form ]

powder to crystal
[pka]

-1.73±0.20(Predicted)
[color ]

White to Light yellow
[BRN ]

383756
[InChI]

InChI=1S/C8H6N2O2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H,9H2
[InChIKey]

KSILMCDYDAKOJD-UHFFFAOYSA-N
[SMILES]

C1(=O)C2=C(C=CC=C2)C(=O)N1N
[CAS DataBase Reference]

1875-48-5(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H315-H317-H319-H334-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R42/43:May cause sensitization by inhalation and skin contact .
[Safety Statements ]

S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[WGK Germany ]

3
[F ]

9
[HS Code ]

29251900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

white to off-white crystalline powder
[Uses]

It is employed in the aziridination of chiral N-enoyl sultams. It is also used in the synthesis of n-phthalimidoaziridines
[Purification Methods]

The imide has been recrystallised from 96% EtOH (solubility is ~2% at boiling temperature) to form a yellow solution. It sublimes in vacuo at ca 150o. It solidifies after melting, and remelts at 338-341o (see phthalhydrazide in “Heterocyclic Compounds, Chapter 4”). [Beilstein 22/11 V 122.]
Spectrum DetailBack Directory
[Spectrum Detail]

N-AMINOPHTHALIMIDE(1875-48-5)MS
N-AMINOPHTHALIMIDE(1875-48-5)1HNMR
N-AMINOPHTHALIMIDE(1875-48-5)13CNMR
N-AMINOPHTHALIMIDE(1875-48-5)IR1
N-AMINOPHTHALIMIDE(1875-48-5)IR2
N-AMINOPHTHALIMIDE(1875-48-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N-Aminophthalimide, tech., 90%(1875-48-5)
[Alfa Aesar]

N-Aminophthalimide, 94%(1875-48-5)
[Sigma Aldrich]

1875-48-5(sigmaaldrich)
[TCI AMERICA]

N-Aminophthalimide,>98.0%(LC)(1875-48-5)
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