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192138-05-9

192138-05-9 Structure

192138-05-9 Structure
IdentificationBack Directory
[Name]

(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
[CAS]

192138-05-9
[Synonyms]

SL-A121-1
(R)-(6,6′
(R)-3,5-t-Bu-MeOBIPHEP
-Dimethoxybiphenyl-2,2′
-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine
(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine]
(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl
(R)-2,2'-Bis[bis(3,5-di-tert-butylphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl
(3-tert-butylphenyl)-[2-[2-(3-propan-2-ylphenyl)phosphanylphenyl]phenyl]phosphane
(R)-(+)-2,2''-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl
(R)-(+)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl
(R)-(+)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl
(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(+)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)phenyl]-
(R)-3,5-t-Bu-MeOBIPHEP, SL-A121-1, (R)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] >=97%, optical purity ee: >=99%
[Molecular Formula]

C70H96O2P2
[MDL Number]

MFCD09753001
[MOL File]

192138-05-9.mol
[Molecular Weight]

1031.46
Chemical PropertiesBack Directory
[Boiling point ]

856.5±65.0 °C(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

white
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

29319090
Hazard InformationBack Directory
[Chemical Properties]

White powder
[Uses]

(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] can be used as a ligand to prepare:
  • 1,2-Dihydropyridines through Rh-catalyzed cycloaddition of diynes to sulfonimines.
  • Enantiorich disubstituted γ-lactams via intramolecular allylic alkylation reaction using Pd catalyst.
  • A Ru-metal complex, which acts as a hydrogenation catalyst applicable in the synthesis of an organic building block (S)-3-fluoromethyl-γ-butyrolactone.

[General Description]

sold in collaboration with Solvias AG
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