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1365531-98-1

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1365531-98-1 Structure

1365531-98-1 Structure
IdentificationBack Directory
[Name]

(R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-Methoxyphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%
[CAS]

1365531-98-1
[Synonyms]

(R)-2,2'-Bis[bis(4-methoxy-3,5-di-t-butylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl
(R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-Methoxyphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%
(R)-2,2'-Bis[bis(4-Methoxy-3,5-di-t-butylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, Min. 97% (R)-DTBM-Garphos
(R)-2,2'-Bis[bis(4-methoxy-3,5-di-t-butylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (R)-DTBM-Garphos(TM)
[Molecular Formula]

C76H108O8P2
[MDL Number]

MFCD22666441
[MOL File]

1365531-98-1.mol
[Molecular Weight]

1211.61
Chemical PropertiesBack Directory
[Boiling point ]

990.9±65.0 °C(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

crystal
[color ]

white
[Optical Rotation]

[α]22/D +18.0°, c =0.5% in chloroform
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Air Sensitive
[InChIKey]

KACYLFSRRUJDSY-UHFFFAOYSA-N
Safety DataBack Directory
[Symbol(GHS) ]

GHS hazard pictograms
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

Chiral ligand used in the preparation of hydrogenation catalysts with exceptionally high activity and selectivity. Reactions of 1365531-98-1
Hazard InformationBack Directory
[Uses]

Versatile chiral diphosphine ligand.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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