| Identification | Back Directory | [Name]
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) | [CAS]
19529-00-1 | [Synonyms]
Tetrakis(triphenylphosphine)ruthenium dihydride
Dihydridotetrakis(triphenylphosphine)ruthenium(Ⅱ)
TETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) HYDRIDE
dihydridotetrakis(triphenylphosphine)-ruthenium(I
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
Dihydrotetrakis(triphenylphosphine)ruthenium(II), 95%
Dihydridotetrakis(triphenylphosphine)ruthenium(II),97% | [Molecular Formula]
C72H62P4Ru | [MDL Number]
MFCD04126429 | [MOL File]
19529-00-1.mol | [Molecular Weight]
1152.23 |
| Chemical Properties | Back Directory | [Appearance]
ochre lustrous powder | [Melting point ]
181-183 °C(lit.)
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Slightly soluble in benzene, toluene, and THF. | [form ]
Lustrous Powder | [color ]
Ochre | [Sensitive ]
air sensitive | [InChI]
1S/4C18H15P.Ru.2H/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;;; | [InChIKey]
RXFATFKBDIQXLS-UHFFFAOYSA-N | [SMILES]
[RuH2].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12 |
| Hazard Information | Back Directory | [Chemical Properties]
ochre lustrous powder | [Uses]
Catalyst for hydration of nitriles, isomerization of alkynes,Knoevenagel reactions and conjugate additions, and transferhydrogenation | [reaction suitability]
core: ruthenium
reagent type: catalyst | [Synthesis]
The Preparative Method of Dihydridotetrakis(triphenylphosphine)ruthenium(II): prepared from Ruthenium(III) Chloride or ruthenium(III) acetylacetonate by reduction with Triethylaluminum in the presence of Triphenylphosphine in THF or benzene under nitrogen at room temperature. The complex can also be prepared by reacting Dichlorotris(triphenylphosphine)ruthenium(II) with Sodium Borohydride and triphenylphosphine. | [Purification Methods]
Dihydridotetrakis(triphenylphosphine)ruthenium(II) could be recrystallized from benzene, toluene, or THF.
| [Precautions]
Dihydridotetrakis(triphenylphosphine)ruthenium(II) is air and light-sensitive and should be stored under argon in the dark.
|
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-37/39 | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
|
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