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2004-14-0

2004-14-0 Structure

2004-14-0 Structure
IdentificationBack Directory
[Name]

LITHIUM TRIMETHYLSILANOLATE
[CAS]

2004-14-0
[Synonyms]

Trimethylsiloxylithium
Lithium trimethylsiloxide
LITHIUM TRIMETHYLSILANOLATE
TRIMETHYLSILANOL LITHIUM SALT
trimethylsilanollithiumderiv.
Lithiumtrimethylsilanolatepure
lithium,trimethyl(oxido)silane
Lithium trimethylsilanolate 97%
trimethyl-silanolithiumderivative
lithium trimethylsilanolate solution
LITHIUM TRIMETHYLSILANOLATE, 20% in toluene
Lithium trimethylsilanolate,Trimethylsilanol lithium salt
Lithium trimethylsilanolate, 1M solution in THF, AcroSeal
LITHIUM TRIMETHYLSILANOLATE, 1.0M SOLUTI ON IN DICHLOROMETHANE
Lithium trimethylsilanolate, 1M solution in dichloromethane, AcroSeal
LithiuM triMethylsilanolate, 1.0 M solution in Methylene chloride, SpcSeal
[Molecular Formula]

C3H9LiOSi
[MDL Number]

MFCD00075322
[MOL File]

2004-14-0.mol
[Molecular Weight]

96.13
Chemical PropertiesBack Directory
[Boiling point ]

40 °C
[density ]

1.278 g/mL at 25 °C
[vapor pressure ]

24.12 psi ( 55 °C)
[Fp ]

145 °F
[form ]

solid
[Specific Gravity]

0.876
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[BRN ]

3686900
[InChI]

1S/C3H9OSi.Li/c1-5(2,3)4;/h1-3H3;/q-1;+1
[InChIKey]

OXOZHAWWRPCVGL-UHFFFAOYSA-N
[SMILES]

[Li+].C[Si](C)(C)[O-]
Safety DataBack Directory
[Hazard Codes ]

C,T
[Risk Statements ]

34-40-23/24/25
[Safety Statements ]

26-28-36/37/39-45-27-16
[RIDADR ]

UN 3267 8/PG 2
[WGK Germany ]

3
[RTECS ]

VV7175000
[F ]

10-21
[TSCA ]

No
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29310099
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Skin Corr. 1B
Hazard InformationBack Directory
[Uses]


  • Enhanced process and composition control for atomic layer deposition with lithium trimethylsilanolate: This study reports on the novel lithium precursor, lithium trimethylsilanolate (LiTMSO), for atomic layer deposition, comparing it with other lithium precursors for improved process and composition control (Ruud et al., 2017).

  • Trimethylsiloxy based metal complexes as electrolyte additives for high voltage application in lithium ion cells: The paper discusses the synthesis of lithium trimethylsilanolate and its use as an additive to enhance the performance of high voltage lithium ion cells (Imholt et al., 2017).

  • Application of trimethylsilanolate alkali salts in organic synthesis: This review covers various applications of lithium trimethylsilanolate in organic synthesis, highlighting its role in different reactions (Bürglová and Hlaváč, 2018).

[Purification Methods]

Wash it with Et2O and pet ether. It sublimes at 180o/1mm as fine transparent needles. [Tatlock & Rochnow J Org Chem 17 1555 1952, Beilstein 4 IV 3992.] Suspected CARCINOGEN.
Spectrum DetailBack Directory
[Spectrum Detail]

LITHIUM TRIMETHYLSILANOLATE(2004-14-0)Raman
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