ChemicalBook--->CAS DataBase List--->1066-40-6

1066-40-6

1066-40-6 Structure

1066-40-6 Structure
IdentificationBack Directory
[Name]

hydroxytrimethylsilane
[CAS]

1066-40-6
[Synonyms]

Silanole
Trimethylsilanol
Silanol, trimethyl-
hydroxytrimethylsilane
Trimethylhydroxysilane
Silanol,1,1,1-triMethyl-
Medetomidine Impurity 17
TriMethylsilanol >=98.0% (GC)
Trimethylsilanol >=97.5% (GC)
[EINECS(EC#)]

213-914-1
[Molecular Formula]

C3H10OSi
[MDL Number]

MFCD02751657
[MOL File]

1066-40-6.mol
[Molecular Weight]

90.1964
Chemical PropertiesBack Directory
[Appearance]

Colorless clear liquid
[Melting point ]

-4.5 °C
[Boiling point ]

90℃/760Torr
[density ]

0.950
[vapor pressure ]

19-55hPa at 25℃
[refractive index ]

1.3889
[Fp ]

4°(39°F)
[storage temp. ]

Sealed in dry,Store in freezer, under -20°C
[solubility ]

Chloroform (Sparingly), DMSO (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
[form ]

liquid
[pka]

12.67±0.58(Predicted)
[color ]

Clear, colourless
[Specific Gravity]

0.8139
[Water Solubility ]

Soluble in water (1.00 mg/ml).
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[BRN ]

1361356
[Henry's Law Constant]

7.0×10-2 mol/(m3Pa) at 25℃, Xu and Kropscott (2014)
[InChI]

1S/C3H10OSi/c1-5(2,3)4/h4H,1-3H3
[InChIKey]

AAPLIUHOKVUFCC-UHFFFAOYSA-N
[SMILES]

C[Si](C)(C)O
[LogP]

1.19-5.06 at 20-25℃
[NIST Chemistry Reference]

Silanol, trimethyl(1066-40-6)
[EPA Substance Registry System]

Silanol, trimethyl-(1066-40-6)
Hazard InformationBack Directory
[Chemical Properties]

Colorless clear liquid
[Description]

Trimethylsilanol has strong acidity compared with the corresponding carbon alcohols, can react with tetrahydrolithium aluminum, Si-OH bond can be reduced Si-H bond, can be used as a blocking agent for straight-chain polysiloxanes with hydrophobicity, it is the most important intermediate in the preparation of organosilicon alcohol salts and all kinds of polysiloxanes products including silicone oils, silicone rubbers and silicone resins, etc, and it has a wide range of application prospects.
[Uses]

Trimethylsilanol used as a hydrophobic coat on silicate surfaces. Used as an as an antimicrobial agent.
[Synthesis]

Trimethylsilanol is produced by hydrolysis of trimethylchlorosilane.
[Toxics Screening Level]

The initial risk screening level (IRSL) for Trimethylsilanol is 65 μg/m3 based on an annual averaging time.
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H225-H332-H412
[Precautionary statements ]

P210-P233-P240-P241-P273-P304+P340+P312
[Hazard Codes ]

F
[Risk Statements ]

11
[RIDADR ]

UN 1993BF 3 / PGII
[WGK Germany ]

1
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[HS Code ]

29319090
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Inhalation
Aquatic Chronic 3
Flam. Liq. 2
Raw materials And Preparation ProductsBack Directory
[Raw materials]

trimethyl-trityl-silane-->Phosphonic acid, 1H-imidazol-1-yl-, diphenyl ester-->Silane, (4-butylphenyl)trimethyl--->Silane, trimethyl[(trimethylsilyl)methoxy]--->Carbamic acid, [(2R)-2-fluoro-3-(hydroxyphosphinyl)propyl]-, 1,1-dimethylethyl ester, monoammonium salt-->Bis(trimethylsilyloxy)-phosphine-->9-(Trimethylsilyl)fluorene-->O-Trimethylsilyl-tert-butyl peroxide-->1,1,1-Trimethyl-2,2,2-triphenyldisilane-->Benzyloxytrimethylsilane-->1H-Inden-1-yltrimethylsilane-->1-Trimethylsilylmethanol-->(R)-tert-butyl (2-fluoro-3-iodopropyl)carbamate(WXC05333)-->1-Phenyl-2-(trimethylsilyl)acetylene-->Triphenylsilanol-->Trimethylfluorosilane-->Hexamethyldisilazane-->tert-Butyl hydroperoxide
[Preparation Products]

Hexamethyldisiloxane
Spectrum DetailBack Directory
[Spectrum Detail]

hydroxytrimethylsilane(1066-40-6)FT-IR
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