ChemicalBook--->CAS DataBase List--->20244-61-5

20244-61-5

20244-61-5 Structure

20244-61-5 Structure
IdentificationMore
[Name]

2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE
[CAS]

20244-61-5
[Synonyms]

2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIEN-1-ONE
2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE
2,5-Cyclohexadien-1-one, 2,4,4,6-tetrabromo-
2,4,4,6-tetrabromocyclohexa-2,5-dienone
2,2,4,4-Tetrabromo-2,5-Cyclohexadienone
2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE, 90+%
2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one95%
[EINECS(EC#)]

243-638-7
[Molecular Formula]

C6H2Br4O
[MDL Number]

MFCD00001589
[Molecular Weight]

409.7
[MOL File]

20244-61-5.mol
Chemical PropertiesBack Directory
[Appearance]

orange to brown fine crystalline powder
[Melting point ]

120-127 °C
[Boiling point ]

365.8±42.0 °C(Predicted)
[density ]

2.6462 (rough estimate)
[refractive index ]

1.5000 (estimate)
[storage temp. ]

0-6°C
[solubility ]

sol CH2Cl2, Et2O, CHCl3, MeNO2, MeOH
[form ]

Liquid
[color ]

Clear colorless
[Water Solubility ]

Insoluble in water.
[BRN ]

2048028
[CAS DataBase Reference]

20244-61-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[HS Code ]

29147000
Hazard InformationBack Directory
[Chemical Properties]

orange to brown fine crystalline powder
[Uses]

2,4,4,6-Tetrabromo-2,5-cyclohexadienone was used as catalyst for efficient deoxygenation of sulfoxides to their corresponding sulfides with 1,3-dithiane. It was also used as reagent for conversion of alcohols to azides.
[Preparation]

bromination of 2,4,6-tribromophenol with Bromine in acetic acid in the presence of sodium acetate.
preparation of 2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE
[General Description]

2,4,4,6-Tetrabromo-2,5-cyclohexadienone forms solid charge-transfer molecular complexes with 4-(aminomethyl)piperidine and their spectroscopic characteristics were studied.
[storage]

2,4,4,6-Tetrabromo-2,5-cyclohexadienone should be kept in a dark vessel, well-protected from light.
Spectrum DetailBack Directory
[Spectrum Detail]

2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE(20244-61-5)MS
2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE(20244-61-5)1HNMR
2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE(20244-61-5)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one, 95%(20244-61-5)
[Alfa Aesar]

2,4,4,6-Tetrabromo-2,5-cyclohexadienone, 90+%(20244-61-5)
[Sigma Aldrich]

20244-61-5(sigmaaldrich)
[TCI AMERICA]

2,4,4,6-Tetrabromo-2,5-cyclohexadienone,>97.0%(T)(20244-61-5)
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