| Identification | More | [Name]
BORANE-TRIPHENYLPHOSPHINE COMPLEX | [CAS]
2049-55-0 | [Synonyms]
BORANE-TRIPHENYLPHOSPHINE
BORANE-TRIPHENYLPHOSPHINE COMPLEX
TRIPHENYLPHOSPHINE BORANE | [Molecular Formula]
C18H18BP | [MDL Number]
MFCD00012427 | [Molecular Weight]
276.12 | [MOL File]
2049-55-0.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystals with an unpleasant smell | [Melting point ]
189-191 °C (lit.) | [storage temp. ]
Refrigerator | [form ]
Powder | [color ]
White | [Stability:]
Stable. Incompatible with acids, oxidizing agents, acid chlorides, alcohols. May decompose on exposure to air and moisture. | [Sensitive ]
Air & Moisture Sensitive | [InChI]
1S/C18H15P.BH3/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H3 | [InChIKey]
CHVBILDTVBDARQ-UHFFFAOYSA-N | [SMILES]
B.c1ccc(cc1)P(c2ccccc2)c3ccccc3 | [CAS DataBase Reference]
2049-55-0(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
white crystals with an unpleasant smell | [Uses]
Reactant for:
- C-P cross coupling with aryl iodides
- Synthesis of N-heterocyclic carbene borane complexes via Lewis base exchange
- Catalyst-free alcoholysis to deprotect phosphane-boranes
- Undergoing heterolytic activation
- Deprotection via reactions with resin-supported amines
- Insertion of overcrowded silylene into hydroboranes
| [reaction suitability]
reagent type: reductant |
|
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J & K SCIENTIFIC LTD.
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Alfa Aesar
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Energy Chemical
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Maya High Purity Chemicals
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Sigma-Aldrich
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