| Identification | Back Directory | [Name]
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) | [CAS]
205495-66-5 | [Synonyms]
(S,S)TROST LIGAND(NAPHTHYL)
min.94%rostligand(naphthyl)
(S,S)-DACH-naphthyl Trost Ligand
(S,S)-DACH-naphthyl Trost Ligand 95%
1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl)
(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane
N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl),94%
(1S,2S)-1,2-Bis[[[2-(diphenylphosphino)naphthalen-1-yl]carbonyl]amino]cyclohexane
(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(S,S)-DACH-Naphthyl Trost Ligand
(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (S,S)-DACH-Naphthyl Trost Ligand
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(S,S)-DACH-NaphthylTrostLigand | [Molecular Formula]
C52H44N2O2P2 | [MDL Number]
MFCD02684552 | [MOL File]
205495-66-5.mol | [Molecular Weight]
790.87 |
| Chemical Properties | Back Directory | [Appearance]
white to off-white powder | [Melting point ]
232-237 °C | [alpha ]
-65.2° (c 1, CH3OH) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [pka]
13.43±0.40(Predicted) | [color ]
off-white | [Optical Rotation]
[α]20/D -66.0°, c = 1 in methanol | [InChIKey]
VXFKMKXTPXVEMU-ZYBCLOSLSA-N | [SMILES]
O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9 |
| Questions And Answer | Back Directory | [Reactions]
The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and seleno nucleophiles.
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