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205495-66-5

205495-66-5 Structure

205495-66-5 Structure
IdentificationBack Directory
[Name]

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
[CAS]

205495-66-5
[Synonyms]

(S,S)TROST LIGAND(NAPHTHYL)
min.94%rostligand(naphthyl)
(S,S)-DACH-naphthyl Trost Ligand
(S,S)-DACH-naphthyl Trost Ligand 95%
1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl)
(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane
N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl),94%
(1S,2S)-1,2-Bis[[[2-(diphenylphosphino)naphthalen-1-yl]carbonyl]amino]cyclohexane
(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(S,S)-DACH-Naphthyl Trost Ligand
(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (S,S)-DACH-Naphthyl Trost Ligand
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(S,S)-DACH-NaphthylTrostLigand
[Molecular Formula]

C52H44N2O2P2
[MDL Number]

MFCD02684552
[MOL File]

205495-66-5.mol
[Molecular Weight]

790.87
Chemical PropertiesBack Directory
[Appearance]

white to off-white powder
[Melting point ]

232-237 °C
[alpha ]

-65.2° (c 1, CH3OH)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[pka]

13.43±0.40(Predicted)
[color ]

off-white
[Optical Rotation]

[α]20/D -66.0°, c = 1 in methanol
[InChIKey]

VXFKMKXTPXVEMU-ZYBCLOSLSA-N
[SMILES]

O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
Hazard InformationBack Directory
[Chemical Properties]

white to off-white powder
[Uses]

Trost Ligands for Asymmetric Allylic Alkylation
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reactions]

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and seleno nucleophiles. Reactions of 205495-66-5
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