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138517-61-0

138517-61-0 Structure

138517-61-0 Structure
IdentificationBack Directory
[Name]

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
[CAS]

138517-61-0
[Synonyms]

TROST LIGAND
(1R,2R)-(+)-1,2-TROST LIGAND
1R,2R- DHAC-Phenyl Trost Ligand
(R,R)-DACH-phenyl Trost ligand
(R,R)-DACH-phenyl Trost ligand 95%
N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]
Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
(1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl
(1R,2R)-N,N'-(Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide)
(1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphoshinobenzoyl)
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide],99%e.e.
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl
(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(R,R)-DACH-PhenylTrostLigand
[Molecular Formula]

C44H40N2O2P2
[MDL Number]

MFCD01631273
[MOL File]

138517-61-0.mol
[Molecular Weight]

690.75
Chemical PropertiesBack Directory
[Melting point ]

134-136°C
[alpha ]

+130° (c 1.0, methanol)
[Boiling point ]

817.0±65.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[pka]

13.35±0.40(Predicted)
[color ]

white to off-white
[Optical Rotation]

[α]20/D +131°, c = 1 in methanol
[InChIKey]

AXMSEDAJMGFTLR-UHFFFAOYSA-N
[SMILES]

C1(NC(=O)C2=CC=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)CCCCC1NC(=O)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Reactions of 138517-61-0_1
Reactions of 138517-61-0_2
Reactions of 138517-61-0_3
Hazard InformationBack Directory
[Uses]

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