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2104-19-0

2104-19-0 Structure

2104-19-0 Structure
IdentificationMore
[Name]

AZELAIC ACID MONOMETHYL ESTER
[CAS]

2104-19-0
[Synonyms]

8-METHOXYCARBONYLOCTANOIC ACID
AZELAIC ACID MONOMETHYL ESTER
METHYL HYDROGEN AZELATE
MONO-METHYL AZELATE
MONOMETHYL NONANEDIOATE
MONO-METHYL NONANEDIONATE
NONANEDIOIC ACID MONOMETHYL ESTER
8-Carbomethoxyoctanoic acid
9-Methoxy-9-oxononanoic acid
AZELAIC ACID MONOMETHYL ESTER, TECH., 90 %
Azelaic acid monomethyl ester, mono-Methyl nonanedioate, Monomethyl azelate
Azelaic acid hydrogen 1-methyl ester
Nonanedioic acid hydrogen 1-methyl ester
[EINECS(EC#)]

218-275-2
[Molecular Formula]

C10H18O4
[MDL Number]

MFCD00004431
[Molecular Weight]

202.25
[MOL File]

2104-19-0.mol
Chemical PropertiesBack Directory
[Appearance]

Low Melting Solid
[Melting point ]

22-24 °C (lit.)
[Boiling point ]

159-160 °C/3 mmHg (lit.)
[density ]

1.045 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.446(lit.)
[Fp ]

>230 °F
[storage temp. ]

Freezer
[solubility ]

Chloroform, DMSO (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

4.77±0.10(Predicted)
[color ]

Colourless to Pale Yellow Oil
[Water Solubility ]

Not miscible in water.
[BRN ]

1775786
[InChI]

InChI=1S/C10H18O4/c1-14-10(13)8-6-4-2-3-5-7-9(11)12/h2-8H2,1H3,(H,11,12)
[InChIKey]

VVWPSAPZUZXYCM-UHFFFAOYSA-N
[SMILES]

C(OC)(=O)CCCCCCCC(O)=O
[CAS DataBase Reference]

2104-19-0(CAS DataBase Reference)
Questions And AnswerBack Directory
[Preparation]

AZELAIC ACID MONOMETHYL ESTER was prepared by ozone oxidation using methyl oleate as a raw material and a mixture of acetic acid and n-hexane as a solvent. The synthesis conditions for AZELAIC ACID MONOMETHYL ESTER were: V(methyl oleate):V(mixed solvent) = 1:4, ozonation reaction temperature of 10–13 °C, oxidative pyrolysis temperature of 90–95 °C, and oxidative pyrolysis time of 2.5 h. The crude product was purified by molecular distillation. Under these conditions, the yield of AZELAIC ACID MONOMETHYL ESTER was ≥78%, and the purity was ≥96%.
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

29171390
Hazard InformationBack Directory
[Chemical Properties]

Low Melting Solid
[Uses]

Methyl hydrogen azelate is used as pharmaceutical intermediates.
Spectrum DetailBack Directory
[Spectrum Detail]

AZELAIC ACID MONOMETHYL ESTER(2104-19-0)MS
AZELAIC ACID MONOMETHYL ESTER(2104-19-0)1HNMR
AZELAIC ACID MONOMETHYL ESTER(2104-19-0)13CNMR
AZELAIC ACID MONOMETHYL ESTER(2104-19-0)IR1
AZELAIC ACID MONOMETHYL ESTER(2104-19-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Methyl hydrogen azelate, 96%(2104-19-0)
[Sigma Aldrich]

2104-19-0(sigmaaldrich)
[TCI AMERICA]

Monomethyl Azelate,>97.0%(GC)(T)(2104-19-0)
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