| Identification | More | [Name]
CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE | [CAS]
21170-10-5 | [Synonyms]
3A,6A-DIMETHYLPERHYDROPENTALENE-2,5-DIONE
CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE
cis-tetrahydro-3a,6a-dimethylpentalene-2,5(1H,3H)-dione
CIS-1,5-DIMETHYLBICYCLO(3.3.0)OCTANE-3,7-DIONE, 98+%
(3aβ,6aβ)-3a,6a-Dimethyloctahydropentalene-2,5-dione
1β,5β-Dimethylbicyclo[3.3.0]octane-3,7-dione
3a,4,6,6a-Tetrahydro-3aα,6aα-dimethyl-2,5(1H,3H)-pentalenedione
3aβ,6aβ-Dimethyltetrahydropentalene-2,5(1H,4H)-dione | [EINECS(EC#)]
244-255-8 | [Molecular Formula]
C10H14O2 | [MDL Number]
MFCD00003772 | [Molecular Weight]
166.22 | [MOL File]
21170-10-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
228-230 °C(lit.) | [Boiling point ]
254.44°C (rough estimate) | [density ]
1.0060 (rough estimate) | [refractive index ]
1.4930 (estimate) | [form ]
solid | [color ]
Faint yellow/faint beige | [InChI]
1S/C10H14O2/c1-9-3-7(11)5-10(9,2)6-8(12)4-9/h3-6H2,1-2H3/t9-,10+ | [InChIKey]
KGZWVKASYOPUET-AOOOYVTPSA-N | [SMILES]
C[C@]12CC(=O)C[C@@]1(C)CC(=O)C2 | [CAS DataBase Reference]
21170-10-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HS Code ]
2914290090 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
Olefination of cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione with (carbethoxyethylidene)triphenylphospharane under controlled microwave heating has been investigated. It reacts with carbon disulfide, strong base and an alkylating agent in dipolar aprotic solvents to yield racemic mixtures of 2-dialkylthio-methylene compounds. | [Synthesis Reference(s)]
Tetrahedron Letters, 9, p. 4885, 1968 DOI: 10.1016/S0040-4039(00)72784-5 | [General Description]
Olefination of cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione with (carbethoxyethylidene)triphenylphospharane under controlled microwave heating has been investigated. It reacts with carbon disulfide, strong base and an alkylating agent in dipolar aprotic solvents to yield racemic mixtures of 2-dialkylthio-methylene compounds. |
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| Company Name: |
Energy Chemical
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| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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