ChemicalBook--->CAS DataBase List--->21193-75-9

21193-75-9

21193-75-9 Structure

21193-75-9 Structure
IdentificationMore
[Name]

D-Galactal
[CAS]

21193-75-9
[Synonyms]

1,5-ANHYDRO-2-DEOXY-D-LYXO-HEX-1-ENITOL
D-GALACTAL
GALACTAL
GALACTAL, D-
2,6-anhydro-5-deoxy-d-arabino-hex-5-enito
D-Galactat
2-(Hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol
(2R,3R,4R)-2-(hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol
(2R)-2α-(Hydroxymethyl)-3,4-dihydro-2H-pyran-3α,4α-diol
1,5-Anhydro-2-deoxy-D-lyxo-1-hexenitol
1,5-Anhydro-2-deoxy-D-lyxo-hexa-1-enitol
2,6-Anhydro-5-deoxy-D-arabino-hexa-5-enitol
[EINECS(EC#)]

244-264-7
[Molecular Formula]

C6H10O4
[MDL Number]

MFCD00038067
[Molecular Weight]

146.14
[MOL File]

21193-75-9.mol
Chemical PropertiesBack Directory
[Appearance]

White Powder
[Melting point ]

99-103 °C (lit.)
[Boiling point ]

325.5±42.0 °C(Predicted)
[density ]

1.414±0.06 g/cm3(Predicted)
[refractive index ]

-22 ° (C=1.2, MeOH)
[storage temp. ]

2-8°C
[solubility ]

Acetonitrile (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

12.79±0.60(Predicted)
[color ]

White to Off-White
[Optical Rotation]

[α]22/D 21.5°, c = 1.2 in methanol
[BRN ]

81690
[Stability:]

Moisture Sensitive
[InChI]

1S/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6-/m1/s1
[InChIKey]

YVECGMZCTULTIS-HSUXUTPPSA-N
[SMILES]

OC[C@H]1OC=C[C@@H](O)[C@H]1O
[CAS DataBase Reference]

21193-75-9(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

29329990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

White Powder
[Uses]

Important building block for both solution- and solid-phase synthesis of oligosaccharides.
[Uses]

D-Galactal is an important building block for both solution- and solid-phase synthesis of oligosaccharides.
[Definition]

ChEBI: D-galactal is a glycal derived from D-galactopyranose It is a glycal and an anhydrohexose.
[Synthesis]

The preparation of D-galactal in the presence of D-galactose,glycol, water and β-galactosidase.
[Purification Methods]

Recrystallise D-galactal from EtOAc, EtOH or EtOAc/MeOH. [Overend et al. J Chem Soc 675 1950, Wood & Fletcher J Am Chem Soc 79 3234 1957, Distler & Jourdian J Biol Chem 248 6772 1973, Beilstein 17 III/IV 2332.]
Spectrum DetailBack Directory
[Spectrum Detail]

D-Galactal(21193-75-9)1HNMR
D-Galactal(21193-75-9)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

D-Galactal, 95%(21193-75-9)
[Sigma Aldrich]

21193-75-9(sigmaaldrich)
[TCI AMERICA]

D-Galactal,>98.0%(LC)(21193-75-9)
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