| Identification | Back Directory | [Name]
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) | [CAS]
212143-23-2 | [Synonyms]
RuCl2[(R)-binap][(R
Dichloro[(R)-(+)-2,2-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II)
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
Dichloro[(r)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1r,2r)-(+)-1,2-diphenylethylenediamine]ruthenium(ii)min
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),min.90%
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediaMine]rutheniuM(II),RuCl2[(R)-binap][(R,R)-dpen]
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediaMine]rutheniuM(II),90% RuCl2[(R)-binap][(R,R)-dpen]
Ruthenium,[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]dichloro[(1R,2R)-1,2-diphenyl-1,2-ethanediamine-kN1,kN2]-, (OC-6-13)- | [Molecular Formula]
C58H48Cl2N2P2Ru | [MDL Number]
MFCD02684565 | [MOL File]
212143-23-2.mol | [Molecular Weight]
1006.94 |
| Chemical Properties | Back Directory | [Melting point ]
>100°C | [storage temp. ]
?20°C | [form ]
Powder | [color ]
white to pale yellow | [Sensitive ]
air sensitive, store cold | [InChIKey]
PZTVCDSGEXHVBL-ODQAEMFESA-L | [SMILES]
Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.c3ccc(cc3)P(c4ccccc4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9ccccc9)c%10ccccc%10 |
| Questions And Answer | Back Directory | [Reaction]
- Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes.
- Asymmetic hydrogenation of imines.
- Catalysts for deracemization of benzylic alcohols.
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