| Identification | Back Directory | [Name]
3-TRIMETHYLSILYLPROPARGYLMETHACRYLATE, 95% | [CAS]
214268-06-1 | [Synonyms]
3-TRIMETHYLSILYLPROPARGYLMETHACRYLATE, 95%
trimethylsilane-protected propargyl methacrylate
2-Propenoic acid, 2-methyl-, 3-(trimethylsilyl)-2-propyn-1-yl ester
3-(Trimethylsilyl)propargyl methacrylate >=98.0%, contains 200 ppm MEHQ as inhibitor | [Molecular Formula]
C10H16O2Si | [MDL Number]
MFCD29067305 | [MOL File]
214268-06-1.mol | [Molecular Weight]
196.32 |
| Chemical Properties | Back Directory | [Boiling point ]
209.2±23.0 °C(Predicted) | [density ]
0.930±0.06 g/cm3(Predicted) | [storage temp. ]
-20°C | [form ]
liquid | [color ]
colorless to pale yellow |
| Safety Data | Back Directory | [WGK Germany ]
WGK 3 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2 |
| Hazard Information | Back Directory | [Uses]
3-(Trimethylsilyl)propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest. While alkynes offer great promise for post-polymerization functionalization, it is difficult to polymerize bifunctional, alkyne-containing monomers without the synthesis of branched or highly gelled products. 3-(Trimethylsilyl)propargyl methacrylate features a silyl-protected alkyne that can be easily deprotected post-polymerization to yield alkyne-functionalized polymers and copolymers. | [General Description]
3-(Trimethylsilyl)propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest. While alkynes offer great promise for post-polymerization functionalization, it is difficult to polymerize bifunctional, alkyne-containing monomers without the synthesis of branched or highly gelled products. 3-(Trimethylsilyl)propargyl methacrylate features a silyl-protected alkyne that can be easily deprotected post-polymerization to yield alkyne-functionalized polymers and copolymers. |
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| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
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