ChemicalBook--->CAS DataBase List--->77-76-9

77-76-9

77-76-9 Structure

77-76-9 Structure
IdentificationMore
[Name]

2,2-Dimethoxypropane
[CAS]

77-76-9
[Synonyms]

2,2-DIMETHOXYPROPANE
ACETONE DIMETHYL ACETAL
DMP
2,2-dimethoxy-propan
2,2-Dimethyoxypropane
Acetone dimethyl ketal
Propane, 2,2-dimethoxy-
Propane,2,2-dimethoxy-
2 2-DIMETHOXYPROPANE REAGENT GRADE 98%
2,2-DIMETHOXYPROPANE pure
Acetone dimethyl acetal, DMP
C.I. 77769
Dimolybdenum trioxide
Molybdenum oxide (Mo2O3)
2,2-Dimethoxypropane ,98%
[EINECS(EC#)]

201-056-0
[Molecular Formula]

C5H12O2
[MDL Number]

MFCD00008479
[Molecular Weight]

104.15
[MOL File]

77-76-9.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Melting point ]

-47 °C
[Boiling point ]

83 °C (lit.)
[density ]

0.847 g/mL at 25 °C(lit.)
[vapor density ]

3.59 (vs air)
[vapor pressure ]

60 mm Hg ( 15.8 °C)
[refractive index ]

n20/D 1.378(lit.)
[Fp ]

12 °F
[storage temp. ]

Flammables area
[solubility ]

180g/l
[form ]

Liquid
[color ]

Clear colorless
[Specific Gravity]

0.852 (20/4℃)
[Stability:]

Stable. Highly flammable-note low flash point. Vapour may form an explosive mixture with air. May form explosive peroxides when exposed to air. Incompatible with strong oxidizing agents.
[explosive limit]

31%, 58°F
[Water Solubility ]

18 g/100 mL (25 ºC)
[Detection Methods]

GC,NMR
[BRN ]

635678
[Henry's Law Constant]

1.4×10-1 mol/(m3Pa) at 25℃, Ebert et al. (2023)
[InChI]

1S/C5H12O2/c1-5(2,6-3)7-4/h1-4H3
[InChIKey]

HEWZVZIVELJPQZ-UHFFFAOYSA-N
[SMILES]

COC(C)(C)OC
[Surface tension]

21.46mN/m at 298.15K
[CAS DataBase Reference]

77-76-9(CAS DataBase Reference)
[NIST Chemistry Reference]

2,2-Dimethoxypropane(77-76-9)
[Storage Precautions]

Moisture sensitive
[EPA Substance Registry System]

77-76-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H225-H319
[Precautionary statements ]

P210-P233-P240-P241-P242-P305+P351+P338
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R36:Irritating to the eyes.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S9:Keep container in a well-ventilated place .
S37/39:Wear suitable gloves and eye/face protection .
S33:Take precautionary measures against static discharges .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

2
[F ]

10-21
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29110000
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 2
[Toxicity]

LD50 orally in Rabbit: > 2260 mg/kg LD50 dermal Rat > 2100 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2,2-Dimethyl-1,3-dioxolane-->Trimethoxymethane-->Allyl phenyl ether-->Acetone-->Propyne
[Preparation Products]

Doxifluridine-->Succinamic acid-->L-Glutamic acid dimethyl ester hydrochloride-->[1,3]Dioxepino[5,6-c]pyridin-9-ol, 1,5-dihydro-3,3,8-trimethyl--->Propane, 2-methoxy-2-(1-methylethoxy)--->1-Ethoxy-1-methoxypropane-->trans-4-Hydroxy-L-proline methyl ester hydrochloride-->Tetramethyl orthosilicate-->1,3-Dioxan-5-ol, 2,2-dimethyl--->Methyl isopropyl ether-->Ethyl 3,4-O-isopropylideneshikiMate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Acetone dimethyl acetal(77-76-9).msds
Hazard InformationBack Directory
[Chemical Properties]

colourless liquid
[Uses]

2,2-Dimethoxypropane(DMP) is used in histology and considered to be more efficient than ethanol for the dehydration of animal tissue.
[General Description]

2,2-Dimethoxypropane is an organic compound, which may be used as a protecting agent in the process of the synthesis of structurally related alkaloids like narciclasine and lycoricidine using phenylbromide as the starting material.
[Toxics Screening Level]

The ITSL for 2,2-Dimethoxypropane is being set at the default value of 0.1 μg/m3 with annual averaging under 232(1)(i).
Spectrum DetailBack Directory
[Spectrum Detail]

2,2-Dimethoxypropane(77-76-9)MS
2,2-Dimethoxypropane(77-76-9)1HNMR
2,2-Dimethoxypropane(77-76-9)13CNMR
2,2-Dimethoxypropane(77-76-9)IR1
2,2-Dimethoxypropane(77-76-9)IR2
2,2-Dimethoxypropane(77-76-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,2-Dimethoxypropane, 98%(77-76-9)
[Alfa Aesar]

2,2-Dimethoxypropane, 98%(77-76-9)
[Sigma Aldrich]

77-76-9(sigmaaldrich)
[TCI AMERICA]

2,2-Dimethoxypropane,>98.0%(GC)(77-76-9)
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