| Identification | Back Directory | [Name]
3-IODO-4-NITROANISOLE | [CAS]
214279-40-0 | [Synonyms]
3-Iodo-4-nitroanisol
3-IODO-4-NITROANISOLE
4-NITRO-3-IODOANISOLE
3-Iodo-4-nitroanisole,97%
3-Iodo-4-nitroanisole, 97% 5GR
2-Iodo-4-Methoxy-1-nitrobenzene
2-Iodo-4-methoxy-1-nitrobenzene, 3-Iodo-4-nitrophenyl methyl ether | [Molecular Formula]
C7H6INO3 | [MDL Number]
MFCD01320682 | [MOL File]
214279-40-0.mol | [Molecular Weight]
279.03 |
| Chemical Properties | Back Directory | [Appearance]
yellow to orange-brown crystals or | [Melting point ]
68-73 °C
| [Boiling point ]
352.1±27.0 °C(Predicted) | [density ]
1.9259 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Crystals or Crystalline Powder | [color ]
Yellow to orange-brown | [InChI]
InChI=1S/C7H6INO3/c1-12-5-2-3-7(9(10)11)6(8)4-5/h2-4H,1H3 | [InChIKey]
NLTAHTYBZZSCIT-UHFFFAOYSA-N | [SMILES]
C1([N+]([O-])=O)=CC=C(OC)C=C1I |
| Hazard Information | Back Directory | [Chemical Properties]
yellow to orange-brown crystals or | [Synthesis]
Silak reaction tube equipped with a magnetic stirrer was charged with 6.2 mg of silver sulfate,21.8 mg of copper acetate, 12.5 mg of 2,9-dimethyl-1,10-o-phenanthroline,39.4 mg of 2-nitro-5-methoxybenzoic acid and 45 mg of sodium iodide4 mL of dimethyl sulfoxide. The reaction was heated at 160 ° C for 24 hours with oxygen. After the reaction, distilled water was added to quench the reaction. Extraction with ethyl acetate 3 times, each time 10mL. The combined organic phases are concentrated; 35.2 mg of 2-Iodo-4-methoxy-1-nitrobenzene was obtained in a yield of 63 percent. | [References]
[1] Patent: CN107325002, 2017, A. Location in patent: Paragraph 0133
[2] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421
[3] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803 |
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