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21548-32-3

21548-32-3 Structure

21548-32-3 Structure
IdentificationBack Directory
[Name]

FOSTHIETAN
[CAS]

21548-32-3
[Synonyms]

geofos
cl64475
acconem
ac64475
nem-a-tak
ent27,873
FOSTHIETAN
geofos[qr]
cl64475[qr]
ac64475[qr]
acconem[qr]
Geofos(ACC)
Fosthiethan
ac64,475[qr]
cl64,475[qr]
nem-a-tak[qr]
Fosthietan granules
FOSETAN(FOSTHIETAN)
RHJOIOVESMTJEK-UHFFFAOYSA-N
diethoxyphosphinylimino-2dithietanne-1,3
(diethoxyphosphinylimino)-1,3-dithietane
N-diethoxyphosphoryl-1,3-dithietan-2-imine
(diethoxyphosphinylimino)-1,3-diethietane[qr]
2-(diethoxyphosphinylimino)-1,3-dithietane[qr]
diethyl(1,3-dithiolan-2-ylidene)phosphoramidate
diethyl (1,3-dithietan-2-ylidene)phosphoramidate
diethyl1,3-dithietan-2-ylidenephosphoramidate[qr]
1,3-dithietan-2-ylidene-phosphoramidicacidiethylester
cyclicmethylene(diethoxyphosphinyl)dithioiminocarbonate
O,O-diethyl-N-(1,3-dithietan-2-ylidene) phosphoramidate
cyclicmethylenediethoxyphosphinodithioimidocarbonate[qr]
diethyl 1,3-dithietan-2-ylidenephosphoramidate fosthietan
1,3-dithietan-2-ylidenephosphoramidicaciddiethylester[qr]
Phosphoramidic acid, N-1,3-dithietan-2-ylidene-, diethyl ester
imidocarbonicacid,phosphonodithio-,cyclicmethylenep,p-diethylester
phosphonodithioimidocarbonicacidcyclicmethylenep,p-diethylester[qr]
[EINECS(EC#)]

244-437-7
[Molecular Formula]

C6H12NO3PS2
[MDL Number]

MFCD00128054
[MOL File]

21548-32-3.mol
[Molecular Weight]

241.27
Chemical PropertiesBack Directory
[Appearance]

Fosthietan is a pale yellow oil. It has a mercaptan-like odor.
[Boiling point ]

57.25°C
[density ]

d25 1.3
[refractive index ]

nD25 1.5348
[solubility ]

Chloroform (Slightly), Ethyl Acetate (Slightly)
[form ]

Oil
[pka]

-4.95±0.20(Predicted)
[color ]

Pale Yellow to Light Yellow
[Water Solubility ]

50g/L(25 ºC)
[Stability:]

Moisture Sensitive
[EPA Substance Registry System]

Fosthietan (21548-32-3)
Hazard InformationBack Directory
[Chemical Properties]

Fosthietan is a pale yellow oil. It has a mercaptan-like odor.
[Uses]

Nematocide; insecticide.
[General Description]

Pale yellow liquid with a mercaptan-like odor. Used as a nematocide and insecticide. Not registered as a pesticide in the U.S.
[Reactivity Profile]

Organophosphates, such as FOSTHIETAN, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
[Health Hazard]

FOSTHIETAN is a liquid organophosphorus insecticide. Organic phosphorus insecticides are absorbed by the skin, as well as by the respiratory and gastrointestinal tracts.
[Fire Hazard]

When heated to decomposition, FOSTHIETAN emits very toxic fumes of nitrogen oxides, phosphorus oxides and sulfur oxides. FOSTHIETAN is a liquid organophosphorus insecticide. Container may explode in heat of fire.
[Potential Exposure]

Fosthietan is used as a nematocide and insecticide. Not currently registered as a pesticide in the U.S.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Speed in removing material from skin is of extreme importance. Shampoo hair promptly if con taminated. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi cal attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body tempera ture. Effects may be delayed; keep victim under observation.
[Shipping]

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the presence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas.
[Description]

Fosthietan is a pale yellow oil with a mercaptan-like odor. Molecular weight=241.28; Specific gravity(water=1)=1.3 g/cm3 at 25℃. Hazard Identification(based on NFPA-704 M Rating System): Health 3,Flammability 1, Reactivity 1. Moderately soluble in water.
[Waste Disposal]

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow ing package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
[Definition]

ChEBI: Fosthietan is a phosphoric ester.
[Synthesis Reference(s)]

Journal of Heterocyclic Chemistry, 7, p. 381, 1970 DOI: 10.1002/jhet.5570070221
[storage]

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area away from alkaline material. Where possible, automatically pump liquid from drums or other storagecontainers to process containers.
Safety DataBack Directory
[Hazard Codes ]

T+
[Risk Statements ]

27/28
[Safety Statements ]

36/37-45
[RIDADR ]

3018
[HazardClass ]

6.1(a)
[PackingGroup ]

I
[Hazardous Substances Data]

21548-32-3(Hazardous Substances Data)
[Toxicity]

LD50 in rats, mice (mg/kg): 5, 18 orally (Whitney, Aston)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Phosphorus oxychloride-->Ammonium thiocyanate-->Petroleum crude oil-->Dibromomethane-->ISOTHIOCYANATE, POLYMER-BOUND, 200-400-->Diethyl chlorophosphate
Tags:21548-32-3 Related Product Information