| Identification | Back Directory | [Name]
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE | [CAS]
21797-13-7 | [Synonyms]
NSC 307191
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
Tetrakis(acetonitrile)palladium(II)tetrafluoroborate,99%
PALLADIUM(II) TETRAFLUOROBORATE-TETRAACETONITRILE COMPLEX
TETRAKIS(ACETONITRILE)PALLADIUM(II) BIS(TETRAFLUOROBORATE)
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE (30%PD)
Tetrakis(acetonitrile)palladiuM(II) tetrafluoroborate, 99% 1GR
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, min. 98%
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, Pd 23.9% | [Molecular Formula]
C8H12B2F8N4Pd | [MDL Number]
MFCD00043297 | [MOL File]
21797-13-7.mol | [Molecular Weight]
444.24 |
| Chemical Properties | Back Directory | [Appearance]
Yellow powder | [Melting point ]
230 °C (dec.)(lit.)
| [storage temp. ]
2-8°C | [form ]
Powder | [color ]
Yellow | [Water Solubility ]
Soluble in water | [Sensitive ]
Air Sensitive | [InChI]
1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2 | [InChIKey]
YWMRPVUMBTVUEX-UHFFFAOYSA-N | [SMILES]
[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow powder | [Uses]
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Reactant involved in:
- Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands
Precursor for:
- Synthesis of dendritic SCS-pincer palladium complexes
- Palladium complexes of click ligands
- Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
| [Uses]
Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation. | [General Description]
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20 | [Safety Statements ]
22-36/37/39-38 | [RIDADR ]
UN2811 | [WGK Germany ]
3
| [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Inhalation |
|
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