| Identification | Back Directory | [Name]
Tetrakis(acetonitrile)copper(I) tetrafluoroborate | [CAS]
15418-29-8 | [Synonyms]
Cu(MeCN)4BF4
e)copper(I) TetrafL
Tetrakis(acetonitriL
Tetra(acetonitrile)copper(1+) tetraflu
Tetra(acetonitrile)copper(1+) tetrafluoroborate
Copper(I) tetra(acetonitrile) tetrafluoroborate
TETRAKIS(ACETONITRILE)COPPER(1)TETRAFLUORO BORATE
Copper(1+) tetrafluoroborate acetonitrile (1:1:4)
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Tetrakis(acetonitrile)copper(I) tetrafluoroborate 97%
Copper(1+), tetrakis(acetonitrile)-, (T-4)-, tetrafluoroborate(1-)
Tetrakis(acetonitrile)copper(I) tetrafluoroborate ISO 9001：2015 REACH | [Molecular Formula]
C8H12BCuF4N4 | [MDL Number]
MFCD09265110 | [MOL File]
15418-29-8.mol | [Molecular Weight]
314.558 |
| Chemical Properties | Back Directory | [Melting point ]
164 °C(dec.) | [density ]
1.466 g cm-3 | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
soluble in toluene, CH2Cl2, MeCN. | [form ]
powder to crystal | [color ]
White to Almost white | [Decomposition ]
270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition) | [InChI]
InChI=1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1 | [InChIKey]
YZGSKMIIVMCEFE-UHFFFAOYSA-N | [SMILES]
[B+3]([F-])([F-])([F-])[F-].[Cu+](N#CC)(N#CC)(N#CC)N#CC |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN 1759 8/PG 2 | [WGK Germany ]
3 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29269090 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
White crystalline powder | [Uses]
Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction. | [General Description]
This product has been enhanced for catalytic efficiency. | [reaction suitability]
core: copper
reagent type: catalyst | [Synthesis]
The Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.
| [Precautions]
Irritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.
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