ChemicalBook--->CAS DataBase List--->15418-29-8

15418-29-8

15418-29-8 Structure

15418-29-8 Structure
IdentificationBack Directory
[Name]

Tetrakis(acetonitrile)copper(I) tetrafluoroborate
[CAS]

15418-29-8
[Synonyms]

Cu(MeCN)4BF4
e)copper(I) TetrafL
Tetrakis(acetonitriL
Tetra(acetonitrile)copper(1+) tetraflu
Tetra(acetonitrile)copper(1+) tetrafluoroborate
Copper(I) tetra(acetonitrile) tetrafluoroborate
TETRAKIS(ACETONITRILE)COPPER(1)TETRAFLUORO BORATE
Copper(1+) tetrafluoroborate acetonitrile (1:1:4)
Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Tetrakis(acetonitrile)copper(I) tetrafluoroborate 97%
Copper(1+), tetrakis(acetonitrile)-, (T-4)-, tetrafluoroborate(1-)
Tetrakis(acetonitrile)copper(I) tetrafluoroborate ISO 9001:2015 REACH
[Molecular Formula]

C8H12BCuF4N4
[MDL Number]

MFCD09265110
[MOL File]

15418-29-8.mol
[Molecular Weight]

314.558
Chemical PropertiesBack Directory
[Melting point ]

164 °C(dec.)
[density ]

1.466 g cm-3
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

soluble in toluene, CH2Cl2, MeCN.
[form ]

powder to crystal
[color ]

White to Almost white
[Decomposition ]

270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition)
[InChI]

InChI=1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1
[InChIKey]

YZGSKMIIVMCEFE-UHFFFAOYSA-N
[SMILES]

[B+3]([F-])([F-])([F-])[F-].[Cu+](N#CC)(N#CC)(N#CC)N#CC
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 1759 8/PG 2
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29269090
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Skin Corr. 1B
Hazard InformationBack Directory
[Chemical Properties]

White crystalline powder
[Uses]

Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.
[General Description]

This product has been enhanced for catalytic efficiency.
[reaction suitability]

core: copper
reagent type: catalyst
[Synthesis]

The Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.
[Precautions]

Irritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.
15418-29-8 suppliers list
Company Name: TCI (Shanghai) Development Co., Ltd.  Gold
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: Shanghai Bihe Biochemical Technology Co., Ltd  Gold
Telephone: 13816464724
Website: http://www.bihebio.com/
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Accela ChemBio Co.,Ltd.  
Telephone: 021-50795510 4000665055
Website: http://www.shao-yuan.com/
Company Name: Nanjing Chemlin Chemical Co., Ltd  
Telephone: 025-83697070 13770331960
Website: www.echemlin.cn
Company Name: Nanjin Cynthia chemicals Technology Co.,Ltd  
Telephone: 0550-5618439 15951861180
Website: http://www.cynthiachem.com
Company Name: Thermo Fisher Scientific  
Telephone: 800-810-5118
Website: www.thermo.com.cn
Company Name: Zhengzhou HongSheng Pharmaceutical Co., Ltd.  
Telephone: 0371-0371-13526885213 15637198702
Website: http://www.hsyykj.cn
Company Name: Shanghai Xingui Biotechnology Co., Ltd.  
Telephone: 15121041756
Website: www.ansitan.com
Company Name: Shanghai Macklin Biochemical Co.,Ltd.  
Telephone: 15221275939 15221275939
Website: www.macklin.cn
Company Name: Hangzhou J&H Chemical Co., Ltd.  
Telephone: 0571-87396432
Website: www.jhechem.com
Company Name: Changsha Jing Kang New Material Technology Co., Ltd.  
Telephone: 0731-85118349 18874718518
Website: www.jbiochem.com
Company Name: Sigma-Aldrich  
Telephone: 021-61415566 800-8193336
Website: https://www.sigmaaldrich.cn
Company Name: Shanghai Synchem Technology Co., Ltd.  
Telephone: 021-64502386 18017349250
Website: http://www.syn-chem.cn
Company Name: Shanghai YuanYe Biotechnology Co., Ltd.  
Telephone: 15026964105
Website: www.shyuanye.com
Company Name: Shandong Xiya Chemical Co., Ltd.  
Telephone: 4009903999 13395398332
Website: http://www.xiyashiji.com
Tags:15418-29-8 Related Product Information
58452-28-1 14735-84-3 21797-13-7 93556-88-8 429-06-1