| Identification | Back Directory | [Name]
2,5-DI-TERT-BUTYLANILINE | [CAS]
21860-03-7 | [Synonyms]
2,5-DI-TERT-BUTYLANILINE
2,5-Di-tert-butylaniline 99%
2,5-di-tert-butylbenzenamine
Benzenamine, 2,5-bis(1,1-dimethylethyl)- | [Molecular Formula]
C14H23N | [MDL Number]
MFCD00010338 | [MOL File]
21860-03-7.mol | [Molecular Weight]
205.34 |
| Hazard Information | Back Directory | [Uses]
2,5-Di-tert-butylaniline has been used in the preparation of:
- new rigid bidentate nitrogen ligands 1,2-bis[(2,5-di-tert-butylphenyl)imino]acenaphthene (dtb-BIAN)
- N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide
| [Purification Methods]
The aniline recrystallises from EtOH in fine needles after steam distillation. It has a pKa2 5 of 3.58 (50% aqueous EtOH). The tosylate has m 164o (from AcOH). [Bell & Wilson J Chem Soc 2340 1956, Carpenter et al. J Org Chem 16 586 1951, Bartlett et al. J Am Chem Soc 76 2349 1954, Beilstein 12 IV 2891.] |
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Sigma-Aldrich
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