| Identification | Back Directory | [Name]
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) | [CAS]
220114-03-4 | [Synonyms]
Dichloro{(S)-(-)-2,2'
RuCl2[(S)-xylbinap][(S,S)-dpen]
RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN]
-bis[di(3,5-xylyl)phosphino]-1,1'
-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen] | [Molecular Formula]
C66H64Cl2N2P2Ru | [MDL Number]
MFCD09753030 | [MOL File]
220114-03-4.mol | [Molecular Weight]
1006.96 |
| Chemical Properties | Back Directory | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
yellow | [Sensitive ]
air sensitive | [InChIKey]
HYMSONXJNGZZBM-LISIALKWSA-L | [SMILES]
Cl[Ru]Cl.N[C@H]([C@@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10 |
| Questions And Answer | Back Directory | [Reactions]
- Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes.
- Asymmetic hydrogenation of imines.
- Catalysts for deracemization of benzylic alcohols.
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