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220114-03-4

220114-03-4 Structure

220114-03-4 Structure
IdentificationBack Directory
[Name]

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
[CAS]

220114-03-4
[Synonyms]

Dichloro{(S)-(-)-2,2'
RuCl2[(S)-xylbinap][(S,S)-dpen]
RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN]
-bis[di(3,5-xylyl)phosphino]-1,1'
-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen]
[Molecular Formula]

C66H64Cl2N2P2Ru
[MDL Number]

MFCD09753030
[MOL File]

220114-03-4.mol
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

yellow
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[WGK Germany ]

3
[HS Code ]

2843.90.0000
Questions And AnswerBack Directory
[Reactions]

  1. Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes.
  2. Asymmetic hydrogenation of imines.
  3. Catalysts for deracemization of benzylic alcohols. 
Reactions of 220114-03-4
Hazard InformationBack Directory
[Uses]

Takasago Ligands and Complexes for Asymmetric Reactions
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