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22112-78-3

22112-78-3 Structure

22112-78-3 Structure
IdentificationBack Directory
[Name]

5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE
[CAS]

22112-78-3
[Synonyms]

TMPP
tetraanisylporphin
RARECHEM AS SA 0033
MESO-TETRAANISYLPORPHYRIN
TETRAMETHOXYPHENYLPORPHYRIN
Tetra(p-methoxyphenyl)porphyrin
Tetrakis(4-methoxyphenyl)porphine
Tetrakis(p-methoxyphenyl)porphyrin
meso-Tetra (4-methoxyphenyl) Porphine
meso-tetrakis-(4-methoxyphenyl)porphyrin
5 10 15 20-TETRAKIS(4-METHOXYPHENYL)- &
tetrakis(4-methoxyphenyl)-21H,23H-porphine
5,10,15,20-Tetrakis(4-methoxyphenyl)porphine
Porphine, 5,10,15,20-tetrakis(p-methoxyphenyl)-
5,10,15,20-Tetra(4-methoxyphenyl)-21H,23H-porphyrin
5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE
5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHYRIN
5,10,15,20-Tetrakis(p-methoxyphenyl)-21H,23H-porphyrin
21H,23H-Porphine, 5,10,15,20-tetrakis(4-methoxyphenyl)-
5,10,15,20-tetrakis(4-methoxyphenyl)-21,22-dihydroporphine
5,10,15,20-tetrakis(4-methoxyphenyl)-21,22-dihydroporphyrin
4-methoxy-1-[7,12,17-tris(4-methoxyphenyl)-21,22,23,24-tetraazapentacyclo[16.2 .1.1
[Molecular Formula]

C48H38N4O4
[MDL Number]

MFCD00012072
[MOL File]

22112-78-3.mol
[Molecular Weight]

734.84
Chemical PropertiesBack Directory
[Melting point ]

>27 °C
[Boiling point ]

~248 °C at 760 Torr
[density ]

1.253±0.06 g/cm3(Predicted)
[storage temp. ]

room temp
[form ]

powder to crystal
[color ]

Dark red to Dark purple to Dark blue
[Appearance]

Dark red to dark purple to dark blue powder crystals
[λmax]

424 nm
653 nm (2nd)
[InChIKey]

PJOJZHHAECOAFH-PJEPRTEXSA-N
[SMILES]

C1(C2=CC=C(OC)C=C2)=C2N=C(C(C3=CC=C(OC)C=C3)=C3NC(=C(C4=CC=C(OC)C=C4)C4=NC(=C(C5=CC=C(OC)C=C5)C5NC1=CC=5)C=C4)C=C3)C=C2 |c:22,t:9,25,38|
[CAS DataBase Reference]

22112-78-3
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

29339900
Hazard InformationBack Directory
[Description]

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine is a synthetic porphyrin derivative with significant applications in various fields. Its unique photophysical properties make it a valuable compound for use in optical sensors and photodynamic therapy (PDT). For example, it has been extensively studied for its triplet state characteristics, which show that it is an effective photosensitizer with high triplet quantum yield (0.63-0.84), long triplet lifetime (around 300 ns in the presence of air), and high quantum yield for singlet oxygen production (ΦΔ≈0.7) . These properties make it a promising candidate for PDT applications, where it can generate reactive oxygen species to destroy cancer cells. Additionally, its derivatives, such as metal complexes, have been used in the development of optical waveguide sensors.

[Uses]

diagnostic assay manufacturing
hematology
histology
[General Description]

5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine is an achiral porphyrin derivative. It forms chiral supramolecular assemblies via spontaneous symmetry breaking at the air or water interface.
Spectrum DetailBack Directory
[Spectrum Detail]

5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE(22112-78-3)1HNMR
5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE(22112-78-3)IR
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