ChemicalBook--->CAS DataBase List--->917-23-7

917-23-7

917-23-7 Structure

917-23-7 Structure
IdentificationBack Directory
[Name]

TPP
[CAS]

917-23-7
[Synonyms]

MTPP
(Chlorin free)
RARECHEM AS SA 0001
TETRAPHENYLPORPHINE
TETRAPHENYLPORFYRIN
TETRAPHENYLPORPHYRIN
LABOTEST-BB LT00441025
MESO-TETRAPHENYLPORPHINE
MESO-TETRAPHENYLPROPHYRIN
MESO-TETRAPHENYLPORPHYRIN
Tetraphenylporphyrin 
meso-Tetraphenylporphyrine
A B G D-TETRAPHENYLPORPHINE
TPP (=Tetraphenylporphyrin)
Meso-Tetraphenylporphine 1GR
Meso-Tetraphenylporphine 5GR
meso-Tetraphenylprophyrin99+%
5,10,15,20-TETRAPHENYLPORPHIN
TETRAPHENYLPORPHINE METAL FREE
5,10,15,20-TETRAPHENYLPORPHINE
meso-Tetraphenylporphyrin ,97%
Tetraphenylporphinechlorinefree
5,10,15,20-Tetraphenylporphyrin
meso-Tetraphenylporphyrin
Porphine, 5,10,15,20-tetraphenyl-
5,10,15,20-Tetrakisphenylporphyrin
Tetraphenylporphine (Chlorin free)
5,10,15,20-Tetraphenylporphin, TPP
Tetraphenylporphyrin (Chlorin free)
meso-Tetraphenylporphine,lowchlorine
meso-Tetraphenylporphine, chlorin free
23h-porphine,5,10,15,20-tetraphenyl-21
5,10,15,20-Tetraphenyl-21H,23H-prophine
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE
meso-Tetraphenylporphine, chlorine free
5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN
21H,23H-Porphine, 5,10,15,20-tetraphenyl-
alpha,beta,gamma,delta-Tetraphenylporphine
TetraphenylporphineTPPchlorinfreevioletxtl
ALPHA,BETA,GAMMA,EPSILON-TETRAPHENYLPORPHIN
meso-Tetraphenylporphine TPP (chlorin free)
MESO-TETRAPHENYLPORPHYRIN, FOR FLUOR-ESC ENCE
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE, 99+%
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE, 97% TPP
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE, 99+% TPP
TetraphenylporphineminTPPcontainschlorinpurplextl.
meso-Tetraphenylporphine (contains 1-3% chlorin),97%
MESO-TETRAPHENYLPORPHINE TPP (CONTAINS 1-3% CHLORIN)
meso-Tetraphenylporphine,min.97%TPP(contains1-3%chlorin)
MESO-TETRAPHENYLPORPHINE 97+% TPP (CONTAINS 1-3% CHLORIN)
meso-Tetraphenylporphine (contains 1-3% chlorin),97% TPP
MESO-TETRAPHENYLPORPHYRIN, FOR FLUORES-C ENCE, CHLORIN FREE
TPP (=Tetraphenylporphine) [Ultra-high sensitive spectrophotometric reagent for Cu]
TPP (=Tetraphenylporphyrin) [Ultra-high sensitive spectrophotometric reagent for Cu]
3-[(4-aMino-2-MethylpyriMidin-5-yl)Methyl]-5-(2-{[hydroxy(phosphonooxy)phosphoryl]oxy}ethyl)-4-Methyl-1,3-thiazol-3-iuM
[EINECS(EC#)]

213-025-9
[Molecular Formula]

C44H30N4
[MDL Number]

MFCD00011680
[MOL File]

917-23-7.mol
[Molecular Weight]

614.74
Chemical PropertiesBack Directory
[Appearance]

purple glistening crystalline powder
[Melting point ]

300 °C
[Boiling point ]

648.45°C (rough estimate)
[density ]

1.5288 (rough estimate)
[refractive index ]

1.7030 (estimate)
[storage temp. ]

2-8°C
[solubility ]

dichloromethane: soluble
[form ]

Glistening Crystalline Powder
[color ]

Blue to purple
[Water Solubility ]

Insoluble in water.
[ε(extinction coefficient)]

≥3500 at 480-486nm in toluene
≥4000 at 647-653nm in toluene
≥5000 at 589-595 nm in toluene
≥8000 at 546-552nm in toluene
[λmax]

514 nm
[BRN ]

379542
[Stability:]

Light Sensitive
[Major Application]

diagnostic assay manufacturing
hematology
histology
[InChIKey]

YNHJECZULSZAQK-LWQDQPMZSA-N
[SMILES]

c1ccc(cc1)-c2c3ccc(n3)c(-c4ccccc4)c5ccc([nH]5)c(-c6ccccc6)c7ccc(n7)c(-c8ccccc8)c9ccc2[nH]9
[EPA Substance Registry System]

21H,23H-Porphine, 5,10,15,20-tetraphenyl- (917-23-7)
Hazard InformationBack Directory
[Chemical Properties]

purple glistening crystalline powder
[Description]

Tetraphenylporphyrin is a photosensitizer that is commonly used to form complexes with metals. Tetraphenylporphyrin complexes are inhibitors of microtubule assembly in human cervix carcinoma cells.

[Uses]

meso-Tetraphenylporphine is a photosensitizer that is often used to create coordination complexes with metals such as cobalt and rhodium. Cobalt meso-tetraphenylporphrine is used as a hydrogen catalyst. Meso-tetraphenylporphrine compounds are used as inhibitors of microtubule assembly in human cervix carcinoma cells.
[Application]

Tetraphenylporphyrin, abbreviated TPP or H2TPP, is a synthetic heterocyclic compound that resembles naturally occurring porphyrins. . . . H2TPP is a photosensitizer for the production of singlet oxygen.
[Definition]

ChEBI: Tetraphenylporphyrin is a meso-substituted porphyrin and a phenylporphyrin.
[Biological Activity]

Tetraphenylporphyrin serves as an efficient inhibitor for Mg and its alloys. It is mainly used as a porphyrin moietyin the preparation of ligand and introduction of metal in porphyrin.
[Purification Methods]

Purify TPP by chromatography on neutral (Grade I) alumina, and recrystallisation from CH2Cl2/MeOH or *C6H6. It forms complexes with metals. [Yamashita et al. J Phys Chem 91 3055 1987, Beilstein 26 III/IV 1958.]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[F ]

8-10-23
[TSCA ]

Yes
[HS Code ]

29349990
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Magnesium chloride-->5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphine
[Preparation Products]

Glass fiber reinforced plastic cooling tower-->Flame retardant master batch-->Polyamide resin,modified-->meso-Tetraphenylporphyrin-Pt(II)-->5,15-Di(4-aminophenyl)-10,20-diphenyl porphine-->Magnesium meso-tetraphenylporphine
Spectrum DetailBack Directory
[Spectrum Detail]

TPP(917-23-7)MS
TPP(917-23-7)1HNMR
TPP(917-23-7)IR1
TPP(917-23-7)IR2
TPP(917-23-7)ESR
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