| Identification | More | [Name]
N-Vinylcaprolactam | [CAS]
2235-00-9 | [Synonyms]
1-ethenylazepan-2-one
1-Ethenylhexahydro-2H-azepin-2-one
1-vinylhexahydro-2h-azepin-2-one
N-VINYLCAPROLACTAM
N-VINYL-EPSILON-CAPROLACTAM
VINYLCAPROLACTAM
1-ethenylhexahydro-2h-azepin-2-on
2H-Azepin-2-one, 1-ethenylhexahydro-
n-vinyl-
N-VINYL-E-CAPROLACTAM
1-Ethenyl-2,3,4,5,6,7-hexahydro-1H-azepin-2-one
1-Vinyl-4,5,6,7-tetrahydro-1H-azepine-2(3H)-one
1-Vinylhexahydro-1H-azepine-2-one
N-Vinyl Caprolactam (V-CAP) | [EINECS(EC#)]
218-787-6 | [Molecular Formula]
C8H13NO | [MDL Number]
MFCD00080693 | [Molecular Weight]
139.19 | [MOL File]
2235-00-9.mol |
| Chemical Properties | Back Directory | [Appearance]
solid | [Melting point ]
35-38 °C (dec.) (lit.) | [Boiling point ]
128 °C/21 mmHg (lit.) | [density ]
1.029 g/mL at 25 °C(lit.)
| [vapor pressure ]
3Pa at 20℃ | [refractive index ]
1. | [Fp ]
214 °F
| [storage temp. ]
2-8°C | [form ]
powder to lump to clear liquid | [pka]
-0.91±0.20(Predicted) | [color ]
White or Colorless to Light orange to Yellow | [Odor]
Faint specific odor | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [Water Solubility ]
Soluble in water (partly). | [FreezingPoint ]
34 | [InChI]
1S/C8H13NO/c1-2-9-7-5-3-4-6-8(9)10/h2H,1,3-7H2 | [InChIKey]
JWYVGKFDLWWQJX-UHFFFAOYSA-N | [SMILES]
C=CN1CCCCCC1=O | [LogP]
1.2 at 25℃ | [CAS DataBase Reference]
2235-00-9(CAS DataBase Reference) | [EPA Substance Registry System]
2235-00-9(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS07,GHS08 | [Signal word ]
Danger | [Hazard statements ]
H302+H312-H317-H319-H372 | [Precautionary statements ]
P280-P301+P312+P330-P302+P352+P312-P305+P351+P338-P314 | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R41:Risk of serious damage to eyes. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection . | [WGK Germany ]
3
| [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29337900 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Sens. 1
STOT RE 1 |
| Hazard Information | Back Directory | [Chemical Properties]
solid | [Uses]
N-Vinyl-e-caprolactam (cas# 2235-00-9) is a compound useful in organic synthesis. | [benefits]
N-Vinylcaprolactam serves as a diluent when coating plastics, as it softens the surface thereby aiding adhesion of the cured film. The monomer N-Vinyl caprolactam provides fast curing and low viscosity and is relatively safe in radiation curable ink. Commercial uses of this chemical have also been reported to include use as a kinetic inhibitor for natural gas hydrates when integrated as a polymer.
| [General Description]
N-Vinylcaprolactam (NVCL) is an organo-soluble amphiphilic material that is soluble in solvents like benzene, isobutanol, and isopropanol. It can be used in the preparation of poly(NVCL) by free-radical polymerization at a temperature higher than its melting point. | [Flammability and Explosibility]
Nonflammable | [Safety Profile]
The acute oral LD50 of vinylcaprolactam was determined to be 1114mg/kg in rats. The acute oral LD50 was determined to be 1236mg/kg in male rats and 1049mg/kg in female rats.
| [Synthesis]
Caprolactam and potassium hydroxide were added proportionally in a four-necked flask, evacuated and heated up to 140 ℃, and the potassium salt of caprolactam was produced while dehydrating. The caprolactam raw material, caprolactam potassium salt, polymer | [Potential Exposure]
Consumer: N-vinylcaprolactam is used as a reactive diluent for UV-coatings, -inks and -adhesives as well as a building block for synthesis of paper coatings and will be almost exclusively incorporated into the polymer matrix within consumer products. Therefore, due to the extremely low levels of residual monomer present in consumer products, exposure and subsequent risk is unlikely.
Worker: In industrial settings, N-vinylcaprolactam is manufactured and handled primarily in closed processes which limit exposure. Based on good manufacturing processes and industrial hygiene the occupational health risk associated with N-vinylcaprolactam is low.
Environmental Exposures: N-vinylcaprolactam is inherently biodegradable and has low potential for bioaccumulation. It is soluble in water and has low potential for volatilization. Based on its physical and chemical properties, if n-vinyl caprolactam was released into the environment, it is expected to partition between water and soil. Volatilization from water surfaces is not expected. | [Purification Methods]
Distil it under vacuum and with 0.0015% of 4-tert-butylcatechol as stabilizer. [Beilstein 21 III/IV 3207.] |
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| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
jiliang chemicals
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| Telephone: |
21-62165282 |
| Website: |
http://www.jiliangchem.com |
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