| Identification | More | [Name]
O-(TRIMETHYLSILYL)HYDROXYLAMINE | [CAS]
22737-36-6 | [Synonyms]
AKOS MSC-0140
AMINOXYTRIMETHYLSILANE
O-(TRIMETHYLSILYL)HYDROXYLAMINE
O-(TRIMETHYLSILYL)HYDROXYLAMINE, TECH., 90%
0-Trimethylsilylhydroxylamine
O-(TRIMETHYLSILYL)HYDROXYLAMINE,PRACT | [Molecular Formula]
C3H11NOSi | [MDL Number]
MFCD00010872 | [Molecular Weight]
105.21 | [MOL File]
22737-36-6.mol |
| Questions And Answer | Back Directory | [Synthesis]
The reaction of chlorosilanes with hydroxylamine is the most common method for preparing silazanes. The amine can act as an absorbent for the HCl released during the reaction. The steric hindrance of the hydroxyl groups and substituents on the silicon significantly affects the ease of the reaction and the distribution of the products. The target compound O-(trimethylsilyl)hydroxylamine was prepared using trimethylchlorosilane and hydroxylamine as starting materials. The synthetic reaction formula is shown in the figure below: 
|
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Boiling point ]
98-100 °C(lit.) | [density ]
0.86 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.405(lit.)
| [Fp ]
48 °F
| [storage temp. ]
2-8°C
| [form ]
Liquid | [pka]
3.28±0.70(Predicted) | [color ]
Clear colorless | [Specific Gravity]
0.860 | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [BRN ]
2035893 | [InChI]
1S/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3 | [InChIKey]
AEKHNNJSMVVESS-UHFFFAOYSA-N | [SMILES]
C[Si](C)(C)ON | [CAS DataBase Reference]
22737-36-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2733 3/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [TSCA ]
No | [HazardClass ]
3.1 | [PackingGroup ]
II | [HS Code ]
29310099 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Flam. Liq. 2
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
O-(Trimethylsilyl)hydroxylamine may be used for the preparation of O-trimethylsilyl oxime ethers. | [General Description]
O-(Trimethylsilyl)hydroxylamine is an O-substituted hydroxylamine. It is formed as an intermediate during the trimethylsilyl chloride catalyzed synthesis of α-branched amines. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|