ChemicalBook--->CAS DataBase List--->22784-59-4

22784-59-4

22784-59-4 Structure

22784-59-4 Structure
IdentificationBack Directory
[Name]

BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE
[CAS]

22784-59-4
[Synonyms]

Benzylbis(triphenylphosphine)
trans-benzyl(chloro)bis(triphenyl-phosphine)palla
Benzylbis(triphenylphosphine)palladium(2)chloride
BENZYL(CHLORO)BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)
Benzylbis(triphenylphosphine)palladium(11)chloride
BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE
TRANS-BENZYL (CHLORO) BIS TRIPHENYLPHOSPHINE PD (II)
TRANS-BENZYL(CHLORO)BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)
trans-Benzyl(chloro)bis(triphenylphosphine)palladiuM(II) 500MG
Palladium,chloro(phenylmethyl)bis(triphenylphosphine)-, (SP-4-3)-
[Molecular Formula]

C43H37ClP2Pd
[MDL Number]

MFCD00010395
[MOL File]

22784-59-4.mol
[Molecular Weight]

757.57
Chemical PropertiesBack Directory
[Appearance]

Yellow crystalline powder
[Melting point ]

166-170 °C(lit.)
[storage temp. ]

Freezer
[solubility ]

sol THF, benzene, and other organic solvents
[form ]

Crystalline Powder
[color ]

Yellow
[InChI]

1S/2C18H15P.C7H7.ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-6H,1H2;1H;/q;;;;+1/p-1
[InChIKey]

PVJAZFSARQVMGK-UHFFFAOYSA-M
[SMILES]

Cl[Pd]Cc1ccccc1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
Hazard InformationBack Directory
[Chemical Properties]

Yellow crystalline powder
[Uses]

Catalyst for the cross coupling1 of alkyl-, vinyl-, alkynyl-, and allylstannane groups with acyl chlorides, allyl halides, vinyl triflates, and iodides.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
[Synthesis]

The preparative method of Benzylbis(triphenylphosphine)palladium(II) chloride: may be prepared from benzyl chloride and (Ph3P)4Pd in benzene at room temperature, washed with Et2O, and dried under vacuum.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE(22784-59-4)IR1
BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE(22784-59-4)IR2
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