| Identification | Back Directory | [Name]
BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE | [CAS]
22784-59-4 | [Synonyms]
Benzylbis(triphenylphosphine)
trans-benzyl(chloro)bis(triphenyl-phosphine)palla
Benzylbis(triphenylphosphine)palladium(2)chloride
BENZYL(CHLORO)BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)
Benzylbis(triphenylphosphine)palladium(11)chloride
BENZYLBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) CHLORIDE
TRANS-BENZYL (CHLORO) BIS TRIPHENYLPHOSPHINE PD (II)
TRANS-BENZYL(CHLORO)BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)
trans-Benzyl(chloro)bis(triphenylphosphine)palladiuM(II) 500MG
Palladium,chloro(phenylmethyl)bis(triphenylphosphine)-, (SP-4-3)- | [Molecular Formula]
C43H37ClP2Pd | [MDL Number]
MFCD00010395 | [MOL File]
22784-59-4.mol | [Molecular Weight]
757.57 |
| Chemical Properties | Back Directory | [Appearance]
Yellow crystalline powder | [Melting point ]
166-170 °C(lit.)
| [storage temp. ]
Freezer | [solubility ]
sol THF, benzene, and other organic solvents | [form ]
Crystalline Powder | [color ]
Yellow | [InChI]
1S/2C18H15P.C7H7.ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-6H,1H2;1H;/q;;;;+1/p-1 | [InChIKey]
PVJAZFSARQVMGK-UHFFFAOYSA-M | [SMILES]
Cl[Pd]Cc1ccccc1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7 |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow crystalline powder | [Uses]
Catalyst for the cross coupling1 of alkyl-, vinyl-, alkynyl-, and allylstannane groups with acyl chlorides, allyl halides, vinyl triflates, and iodides. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | [Synthesis]
The preparative method of Benzylbis(triphenylphosphine)palladium(II) chloride: may be prepared from benzyl chloride and (Ph3P)4Pd in benzene at room temperature, washed with Et2O, and dried under vacuum.
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| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22-36/37/38 | [Safety Statements ]
26-37/39 | [WGK Germany ]
3
| [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
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