| Identification | Back Directory | [Name]
Di(trimethylol propane) | [CAS]
23235-61-2 | [Synonyms]
DTMP
DI-TMP
Ditrimethylol
Einecs 245-509-0
DI(TRIMETHYLOLPROPANE)
Di(trimethylolpropane)>
3,3,4-trimethyl-1,2-dioxetane
Perstorp Di-Trimethylolpropane
Bis (1,1,1-trimethylolpropane)
Bis[2,2-di(hydroxymethyl)butyl] ether
Bis[2-ethyl-2,2-bis(hydroxymethyl)ethyl] Ether
1,3-Propanediol, 2,2-oxybis(methylene)bis2-ethyl-
2,2’-[oxybis(methylene)]bis[2-ethyl-3-propanediol
2,2'-OXYBIS(METHYLENE)BIS(2-ETHYL-1,3-PROPANEDIOL)
3-Propanediol,2,2’-[oxybis(methylene)]bis[2-ethyl-1
2,2'-[oxybis(methylene)]bis[2-ethylpropane-1,3-diol]
2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol
2,2'-(Oxybis(methylene))bis(2-ethylpropane-1,3-diol)(Flakes or Chunks)
Di(trimethylolpropane),2,2′-Oxybis(methylene)bis(2-ethyl-1,3-propanediol) | [EINECS(EC#)]
245-509-0 | [Molecular Formula]
C12H26O5 | [MDL Number]
MFCD00192117 | [MOL File]
23235-61-2.mol | [Molecular Weight]
250.33 |
| Chemical Properties | Back Directory | [Melting point ]
108-111 °C(lit.)
| [Boiling point ]
215 °C4 mm Hg(lit.)
| [density ]
1.0187 (rough estimate) | [vapor pressure ]
0Pa at 25℃ | [refractive index ]
1.4560 (estimate) | [storage temp. ]
Store at room temperature | [solubility ]
soluble in Methanol | [form ]
powder to crystal | [pka]
13.90±0.10(Predicted) | [color ]
White to Almost white | [Water Solubility ]
21g/L at 20℃ | [BRN ]
1860782 | [InChI]
1S/C12H26O5/c1-3-11(5-13,6-14)9-17-10-12(4-2,7-15)8-16/h13-16H,3-10H2,1-2H3 | [InChIKey]
WMYINDVYGQKYMI-UHFFFAOYSA-N | [SMILES]
CCC(CO)(CO)COCC(CC)(CO)CO | [LogP]
0.88 at 25℃ | [EPA Substance Registry System]
1,3-Propanediol, 2,2'-[oxybis(methylene)] bis[2-ethyl-(23235-61-2) |
| Safety Data | Back Directory | [Safety Statements ]
22-24/25 | [WGK Germany ]
3
| [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HS Code ]
29094990 | [Storage Class]
13 - Non Combustible Solids |
| Hazard Information | Back Directory | [Description]
Di(trimethylol propane), Di-TMP, 2,2-[oxybis(methylene)]-bis(2-ethyl)-1,3-propanediol is a colorless and crystalline substance (mp 112 – 114 ℃), only slightly soluble in water at ambient temperature (2.6 g/100 g at 25 ℃).It is a byproduct of 2-ethyl-2-hydroxymethyl-1,3-propanediol (TMP) production and can be isolated from the residue of the TMP distillation step. Newer investigations show that ditrimethylolpropane can be prepared in high yield and selectivity by the reaction of TMP, formaldehyde, and 2-ethylacrolein.
| [Uses]
Di(trimethylolpropane) can be used for the synthesis of lipase catalyzed hyperbranched polymers. It can also be used in the formation of biodegradable polymers for drug delivery applications. | [Application]
Di-trimethylolpropane is mainly used for production of acrylic monomers and oligomers for radiation-curable coatings and inks, including lithography, ink jet, and flexography inks. Di-TMP tetraacrylate has a very high reactivity, low skin irritation, and gives coatings with good scratch and chemical resistance, hence it also find uses in hard coats for electronics. Di-TMP is used as costabilizer in some lead-free PVC stabilizers based on calcium – zinc. Minor uses are in coating resins and synthetic lubricants.
| [Synthesis Reference(s)]
Canadian Journal of Chemistry, 53, p. 1103, 1975 DOI: 10.1139/v75-154 | [General Description]
Di(trimethylolpropane) is a monomeric unit with primary hydroxyl groups, that can be used as a tetrafunctional core molecule. | [Flammability and Explosibility]
Notclassified |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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