| Identification | More | [Name]
TRIMESITYLPHOSPHINE | [CAS]
23897-15-6 | [Synonyms]
TRIMESITYLPHOSPHINE
TRIS(2,4,6-TRIMETHYLPHENYL)PHOSPHINE
TRIS(2,4,6-TRIMETHYLPHENYL)PHOSPHINE, 97 %
Trimesitylphosphine,98%
Trismesitylphosphine | [Molecular Formula]
C27H33P | [MDL Number]
MFCD00014912 | [Molecular Weight]
388.52 | [MOL File]
23897-15-6.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
185-188 °C (lit.) | [Boiling point ]
491.1±45.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
white | [Water Solubility ]
Insoluble in water. | [InChI]
1S/C27H33P/c1-16-10-19(4)25(20(5)11-16)28(26-21(6)12-17(2)13-22(26)7)27-23(8)14-18(3)15-24(27)9/h10-15H,1-9H3 | [InChIKey]
IDXDWPWXHTXJMZ-UHFFFAOYSA-N | [SMILES]
Cc1cc(C)c(P(c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)c(C)c1 | [CAS DataBase Reference]
23897-15-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [HS Code ]
29319090 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
It is used as an intermediate in organic synthesis. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand | [Purification Methods]
It recrystallises from EtOH [Boert et al. J Am Chem Soc 109 7781 1987]. The P-methyl iodide has m 269o (yellow powder from EtOH or H2O). [Beilstein 16 H 774.] |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
T&W GROUP
|
| Telephone: |
021-61551611 13296011611 |
| Website: |
www.trustwe.com/ |
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