ChemicalBook--->CAS DataBase List--->24389-25-1

24389-25-1

24389-25-1 Structure

24389-25-1 Structure
IdentificationBack Directory
[Name]

Li difluorophosphate
[CAS]

24389-25-1
[Synonyms]

LiPO2F2
LiPF2O2
Li difluorophosphate
lithium difluorophosphate
Lituium difluorophosphate
Lithium Difluorophosphate (LiPO2F2)
Phosphorodifluoridic acid, lithium salt
lithium difluorophosphate (LiPO2F2 /LiDFP)
Phosphorodifluoridic acid, lithium salt (1:1)
[EINECS(EC#)]

643-080-8
[Molecular Formula]

F2H2LiO2P
[MDL Number]

MFCD32670669
[MOL File]

24389-25-1.mol
[Molecular Weight]

109.92
Chemical PropertiesBack Directory
[density ]

1.979g/cm3 at 20℃
[form ]

Solid:particulate/powder
[Major Application]

battery manufacturing
[InChI]

InChI=1S/F2HO2P.Li.H/c1-5(2,3)4;;/h(H,3,4);;
[InChIKey]

WKKCPZOLQZPXAA-UHFFFAOYSA-N
[SMILES]

P(O)(=O)(F)F.[LiH]
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314-H290
[Precautionary statements ]

P501-P260-P234-P264-P280-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P406-P405
[WGK Germany ]

WGK 3
[REACH Registrations]

Active
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Chronic 2
Eye Dam. 1
Skin Corr. 1B
STOT RE 1
Hazard InformationBack Directory
[Chemical Properties]

Lithium Difluorophosphate (24389-25-1) is a white powder solid with a melting point of 340℃. It can easily absorb moisture in the air and exhibit acidity when exposed to air. It is used as an additive in electrolytes for lithium-ion batteries to enhance the cyclic performance, high-temperature storage performance, and lower the internal resistance of the battery.
[Uses]

Lithium Difluorophosphate, as an additive of electrolyte for rechargeable Lithium-ion battery, effectively reduces the resistance of SEI layer formed on the electrode under low temperature, and reduces self-discharge of the battery. Meanwhile,adding of Lithium Difluorophosphate can reduce the usage of Lithium Hexafluorophosphate(LiPF6).
[Synthesis]

In the closed steel reaction dad, respectively, P2O5, LiF and dry tetrachlorofuran were added to the reaction dad at room temperature, sealed and stirred, cooled down to -40 ° C, and replaced the kettle atmosphere three times with nitrogen, argon or heliu
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