ChemicalBook--->CAS DataBase List--->244761-29-3

244761-29-3

244761-29-3 Structure

244761-29-3 Structure
IdentificationBack Directory
[Name]

Lithium bis(oxalate)borate
[CAS]

244761-29-3
[Synonyms]

LIBOB
CHEMLYTE BO M1
CHEMLYTE BO MX
lithium bis(oxalate)borate
LITHIUM BIS(OXALATO)BORATE
Lithium oxalate boronic acid
Lithium bis(ethanedioato)borate
LITHIUM BIS (OXALATE) BORATE(LiBOB)
Lithium bis(oxalate)borate ISO 9001:2015 REACH
Lithium bis(oxalate)borate LiBOB Lithium bis(ethanedioato)borate
Lithium bis-(oxalato)borate - LiBOB (sbg), standard battery grade
Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium, (T-4)-
lithium,1,4,6,9-tetraoxa-5-boranuidaspiro[4.4]nonane-2,3,7,8-tetrone
LithiuM 2,3,7,8-tetraoxo-1,4,6,9-tetraoxa-5-boraspiro[4.4]nonan-5-uide
Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium (1:1), (T-4)-
[EINECS(EC#)]

456-990-3
[Molecular Formula]

C4BLiO8
[MDL Number]

MFCD07776904
[MOL File]

244761-29-3.mol
[Molecular Weight]

193.79
Chemical PropertiesBack Directory
[Melting point ]

>300°C (lit.)
[vapor pressure ]

0.004Pa at 20℃
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

powder or crystals
[Water Solubility ]

1015g/L at 20℃
[InChI]

InChI=1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1
[InChIKey]

NVQAYVUCVASGDK-UHFFFAOYSA-N
[SMILES]

O=C1C([O-][B+3]2([O-]C(=O)C(=O)[O-]2)[O-]1)=O.[Li+]
[LogP]

0 at 20℃
[EPA Substance Registry System]

Borate(1-), bis[ethanedioato(2-)-.kappa.O1,.kappa.O2]-, lithium, (T-4)- (244761-29-3)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[HS Code ]

29319090
Hazard InformationBack Directory
[Uses]

Lithium bis(oxalate)borate is a new and proprietary conductive salt for the use in high performance batteries like lithium batteries, lithium ion batteries and lithium polymer batteries. The new halide-free product may be used instead of traditional fluorinated compounds like LiPF6, LiBF4, Li-triflate, methanides, imides etc.
[General Description]

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[Flammability and Explosibility]

Nonflammable
[Synthesis]

Yu et al. employed a solid-state reaction using oxalic acid, lithium hydroxide, and boric acid as starting materials for the first time. This was followed by a thermal treatment in the air and a recrystallization process to obtain LiBOB. In addition, LiBOB decomposes into Li2C2O3, B2O3, CO2, and CO at temperatures higher than 300 °C [1].
[References]

[1] Ceren Zor. “Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB).” The Journal of Physical Chemistry C 125 21 (2021): 11310–11317.
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