ChemicalBook--->CAS DataBase List--->251320-86-2

251320-86-2

251320-86-2 Structure

251320-86-2 Structure
IdentificationBack Directory
[Name]

2-(Dicyclohexylphosphino)-2'-methylbiphenyl
[CAS]

251320-86-2
[Synonyms]

Me-phos
98% MePhos
MebiphPCy2
MePhos 97%
2-(Dicyclohexylphosphino)-2'-M
2-Dicyclohexylphosphino-2'-Methylbipheny
2-Methyl-2'-dicyclohexylphosphinobiphenyl
2-(Dicyclolexylphosphino)-2'-methylbiphenyl
2-(DICYCLOHEXYLPHOSPHINO)-2'-METHYLBIPHENYL
2-(DicyclohexylphosphiNA)-2'-Methylbiphenyl
2-Dicyclohexylphenosphino-2’-methyl-biphenyl
2-(Dicyclohexylphosphino)-2'-methylbiphenyl
2-(Dicyclohexylphosphino)-2'-methylbiphenyl,98%
2-Dicyclohexylphosphino-2'-Methylbiphenyl,MePhos
2-Dicyclohexylphosphino-2'-methyl-)-1,1'-biphenyl
2-Dicyclohexylphosphino-2'-Methylbiphenyl,98% MePhos
dicyclohexyl(2'-Methyl-[1,1'-biphenyl]-2-yl)phosphine
2-Dicyclohexylphosphino-2'-methylbiphenyl,min.98%MePhos
PHOSPHINE, DICYCLOHEXYL(2''-METHYL[1,1''-BIPHENYL]-2-YL)-
2-Methyl-2μ-dicyclohexylphosphinobiphenyl, MebiphPCy2, MePhos
2-Dicyclohexylphosphino-2'-methyl-)-1,1'-biphenyl, min. 98% MePhos
[EINECS(EC#)]

607-557-4
[Molecular Formula]

C25H33P
[MDL Number]

MFCD03094577
[MOL File]

251320-86-2.mol
[Molecular Weight]

364.5
Chemical PropertiesBack Directory
[Appearance]

White crystals or crystalline powder
[Melting point ]

107-111 °C
[Boiling point ]

499.3±24.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

soluble in Toluene
[form ]

crystal
[color ]

white
[Water Solubility ]

insoluble
[Sensitive ]

Air Sensitive
[InChI]

InChI=1S/C25H33P/c1-20-12-8-9-17-23(20)24-18-10-11-19-25(24)26(21-13-4-2-5-14-21)22-15-6-3-7-16-22/h8-12,17-19,21-22H,2-7,13-16H2,1H3
[InChIKey]

GPVWUKXZFDHGMZ-UHFFFAOYSA-N
[SMILES]

P(C1CCCCC1)(C1CCCCC1)C1=CC=CC=C1C1=CC=CC=C1C
Hazard InformationBack Directory
[Chemical Properties]

White crystals or crystalline powder
[Uses]

Ligand used for the Pd-catalyzed formation of a-arylketones
[Uses]

suzuki reaction
[reaction suitability]

reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H413
[Precautionary statements ]

P273-P501
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

37/39-26
[WGK Germany ]

3
[TSCA ]

No
[HazardClass ]

IRRITANT
[HS Code ]

29310099
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Ligand used for the Pd-catalyzed formation of a-arylketones.
  2. Ligand used for the Pd-catalyzed amination reaction.
  3. Ligand used for the Pd-catalyzed hydrazone arylation.
  4. Ligand used for the Pd-catalyzed synthesis of 5,5-disubstituted butenolides.
  5. Ligand used for the Pd-catlyzed direct arylation of polyfluorinated arenes at room temperature.
Reactions of 251320-86-2
Spectrum DetailBack Directory
[Spectrum Detail]

2-(Dicyclohexylphosphino)-2'-methylbiphenyl(251320-86-2)1HNMR
2-(Dicyclohexylphosphino)-2'-methylbiphenyl(251320-86-2)31PNMR
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