| Identification | Back Directory | [Name]
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE | [CAS]
261733-18-0 | [Synonyms]
NIXANTPHOS
N-XantPhos 97%
98% NixantPhos
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
4,6-Bis(diphenylphosphino)phenoxazine 97%
4,6-BIS(DIPHENYLPHOSPHINO)-10H-PHENOXAZINE
4,6-Bis(diphenylphosphino)phenoxazine, 98+%
4,6-Bis(diphenylphosphino)phenoxazine, min. 98%
4,6-Bis(diphenylphosphino)phenoxazine, NIXANTPHOS
4,6-Bis(diphenylphosphino)phenoxazine, 98+% NIXANTPHOS
4,6-Bis(diphenylphosphino)phenoxazine,min.98%NIXANTPHOS | [Molecular Formula]
C36H27NOP2 | [MDL Number]
MFCD03788937 | [MOL File]
261733-18-0.mol | [Molecular Weight]
551.55 |
| Chemical Properties | Back Directory | [Melting point ]
256-262 °C
| [Boiling point ]
662.1±55.0 °C(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Powder | [pka]
1.34±0.20(Predicted) | [color ]
white to off-white | [Water Solubility ]
Miscible with water. | [InChIKey]
HSWZLYXRAOXOLL-UHFFFAOYSA-N | [SMILES]
C1=C2C(OC3=C(N2)C=CC=C3P(C2=CC=CC=C2)C2=CC=CC=C2)=C(P(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 | [CAS DataBase Reference]
261733-18-0 |
| Hazard Information | Back Directory | [Uses]
4,6-Bis(Diphenylphosphino)phenoxazine is used as a palladium catalyst in reactions involving the synthesis of triarylmethanes. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings |
| Questions And Answer | Back Directory | [Reactions]
- A large bite-angle chelating bisphosphine that provides high levels of linear-to-branched selectivity in the hydroformylation of alkenes.
- A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides.
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