| Identification | More | [Name]
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) | [CAS]
166330-10-5 | [Synonyms]
2,2'-BIS(DIPHENYLPHOSPHINO)DIPHENYL ETHER
BIS(2-DIPHENYLPHOSPHINOPHENYL)ETHER
DPEPHOS
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
Bisdiphenylphosphinophenylether
Bis(2-diphenylphosphinophenyl)ether, DPEphos
Bis(2-diphenylphosphinophenyl)ether,98%DPEphos
Bis(2-diphenylphosphino)phenylü ether, 98% | [EINECS(EC#)]
678-206-0 | [Molecular Formula]
C36H28OP2 | [MDL Number]
MFCD00233863 | [Molecular Weight]
538.55 | [MOL File]
166330-10-5.mol |
| Chemical Properties | Back Directory | [Appearance]
White to off-white crystalline powder or crystals | [Melting point ]
184-187 °C (lit.) | [Boiling point ]
608.2±40.0 °C(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Crystalline Powder or Crystals | [color ]
White to off-white | [BRN ]
7729718 | [InChIKey]
RYXZOQOZERSHHQ-UHFFFAOYSA-N | [CAS DataBase Reference]
166330-10-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
White to off-white crystalline powder or crystals | [Uses]
suzuki reaction | [General Description]
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| Questions And Answer | Back Directory | [Reaction]
- Useful as a ligand in the Pd-catalyzed formation of diaryl amines.
- Has been recently applied to the C3 benzylation of indoles.
- Has been recently applied to the monoallylation of ammonia.
- Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.
- Ligand used in carbonylation of aryl iodides.
- Ligand used in the direct C-H arylation of benzothiodiazoles.
- Ligand used in stereo-retentive azacyclization of propargylic carbonates.
- Ligand used in palladium catalyzed benzyne trimerization.
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