| Identification | Back Directory | [Name]
BIS(2-METHOXYPHENYL)CHLORPHOSPHINE | [CAS]
263369-88-6 | [Synonyms]
BIS(2-METHOXYPHENYL)CHLORPHOSPHINE
Chlorobis(2-methoxyphenyl)phosphine
Chlorobis(o-methoxyphenyl)phosphine
Bis(2-methoxyphenyl)chlorophosphine,
chloro-bis(2-methoxyphenyl)phosphane
Chlorobis(2-methoxyphenyl)phosphine, 98+%
Phosphinous chloride, P,P-bis(2-methoxyphenyl)- | [EINECS(EC#)]
679-144-7 | [Molecular Formula]
C14H14ClO2P | [MDL Number]
MFCD08064037 | [MOL File]
263369-88-6.mol | [Molecular Weight]
280.69 |
| Chemical Properties | Back Directory | [Melting point ]
111-114°C | [Boiling point ]
408.4±30.0 °C(Predicted) | [Water Solubility ]
Reacts with water. | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C14H14ClO2P/c1-16-11-7-3-5-9-13(11)18(15)14-10-6-4-8-12(14)17-2/h3-10H,1-2H3 | [InChIKey]
PEKLJSZEUFVLKO-UHFFFAOYSA-N | [SMILES]
COc1ccccc1P(Cl)c2ccccc2OC |
| Hazard Information | Back Directory | [Uses]
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
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