ChemicalBook--->CAS DataBase List--->27138-31-4

27138-31-4

27138-31-4 Structure

27138-31-4 Structure
IdentificationMore
[Name]

Oxydipropyl dibenzoate
[CAS]

27138-31-4
[Synonyms]

3,3'-OXYDI-1-PROPANOL DIBENZOATE
BENZOIC ACID N-DIPROPYLENEGLYCOL DIESTER
DIPROPANEDIOL DIBENZOATE
DIPROPYLENE GLYCOL DIBENZOATE
DPGDB
K-FLEX DP
Dipropylenglycoldibenzoate
oxybis-propanodibenzoate
Propanol,oxybis-,dibenzoate
oxydipropyl dibenzoate
DI(PROPYLENE GLYCOL) DIBENZOATE, TECH.,&
3 3-OXYDI-L-PROPANOL DIBENZOATE
DPGDBFDA:21CFR175.105,176.170and176.180
DPG dibenzoate
OXYDIPROPYLENEDIBENZOATE
DI12PROPYLENEGLYCOLDIBENZOATE
Reaktionsprodukt aus 1,2-Dipropylenglykol mit Benzoesure
2-[1-(Benzoyloxy)propan-2-yloxy]propyl benzoate
[EINECS(EC#)]

248-258-5
[Molecular Formula]

C20H22O5
[MDL Number]

MFCD00046063
[Molecular Weight]

342.39
[MOL File]

27138-31-4.mol
Questions And AnswerBack Directory
[Preparation]

Using dipropylene glycol and benzoic acid as raw materials, a direct esterification reaction is carried out at 180–220℃ in the presence of catalysts such as p-toluenesulfonic acid and titanate. The reaction is driven by azeotropic dehydration. After the reaction, unreacted raw materials and low-boiling substances are removed by neutralization, water washing, and vacuum distillation to finally obtain a high-purity dipropylene glycol dibenzoate product.

Chemical PropertiesBack Directory
[Melting point ]

-40
[Boiling point ]

232 °C5 mm Hg(lit.)
[density ]

1.12 g/mL at 25 °C(lit.)
[vapor pressure ]

0Pa at 25℃
[refractive index ]

n20/D 1.528(lit.)
[Fp ]

>230 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Liquid
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents.
[Water Solubility ]

8.69mg/L at 20℃
[Henry's Law Constant]

7.2×102 mol/(m3Pa) at 25℃, Duchowicz et al. (2020)
[Cosmetics Ingredients Functions]

SKIN CONDITIONING - EMOLLIENT
SKIN CONDITIONING
[InChI]

InChI=1S/C20H22O5/c1-15(24-19(21)17-9-5-3-6-10-17)13-23-14-16(2)25-20(22)18-11-7-4-8-12-18/h3-12,15-16H,13-14H2,1-2H3
[InChIKey]

IZYUWBATGXUSIK-UHFFFAOYSA-N
[SMILES]

C1(C=CC=CC=1)C(=O)OC(C)COCC(C)OC(=O)C1=CC=CC=C1
[LogP]

3.9 at 20℃
[CAS DataBase Reference]

27138-31-4(CAS DataBase Reference)
[EPA Substance Registry System]

Dipropylene glycol dibenzoate (27138-31-4)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H412
[Precautionary statements ]

P273
[Hazard Codes ]

N
[Risk Statements ]

51/53
[Safety Statements ]

61
[WGK Germany ]

2
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HS Code ]

29163100
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Aquatic Chronic 3
Hazard InformationBack Directory
[Description]

Di(propylene glycol) dibenzoate (DPGDB) is a benzoate plasticiser characterised by high solubility and environmental friendliness. It is compatible with a wide range of polar polymers and can serve as a substitute for phthalate plasticisers. When used as a plasticiser for polyvinyl alcohol (PVAc), DPGDB can be employed in the manufacture of diamond-coated PVC. Furthermore, studies have shown that for polymers adsorbed onto silica, the plasticiser has no effect when the polymer adsorption amount is 0.81 mg/m². This adsorption amount roughly corresponds to the amount of PVAc tightly bound to silica gel. However, when the adsorption amount increases to 1.42 or 1.81 mg/m², the plasticiser effectively reduces the glass transition temperature (Tg) of the adsorbed polymer[1].
[Uses]

DPGDB may be used as a diluent for the preparation of polysulfone membranes by heat induced phase separation. It finds potential applications in water treatment and food processing. It may also be used as a plasticizer with poly(vinyl) chloride (PVC) for the fabrication of diamond coated PVC.
[General Description]

Di(propylene glycol) dibenzoate (DPGDB) is a widely used plasticizer that has ether linkages linked with two benzoate groups.
[Flammability and Explosibility]

Nonflammable
[References]

[1] Boonta Hetayothin,   Frank D. B.,  Roy A. Cabaniss. (2017). Does Plasticizer Penetrate Tightly Bound Polymer in Adsorbed Poly(vinyl acetate) on Silica? Macromolecules, 50 5, 2092–2102. https://doi.org/10.1021/acs.macromol.7b00022
Spectrum DetailBack Directory
[Spectrum Detail]

Oxydipropyl dibenzoate(27138-31-4)1HNMR
Oxydipropyl dibenzoate(27138-31-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

27138-31-4(sigmaaldrich)
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