| Identification | More | [Name]
2,4-Dimethoxyaniline | [CAS]
2735-04-8 | [Synonyms]
2,4-DIMETHOXYANILINE
2,4-DIMETHOXY BENZAMINE
4-AMINORESORCINOL
AKOS BBS-00003627
2,4-dimethoxy-anilin
2,4-dimethoxy-benzenamin
4-Aminoresorcinol dimethyl ether
Aniline, 2,4-dimethoxy-
aniline,2,4-dimethoxy-[qr]
2,4-dimethoxybenzenamine
2,4-Dimethoxyaniline, 97+%
Benzenamine, 2,4-dimethoxy-
1-Amino-2,4-dimethoxybenzene
2,4-Dimethoxyaniline ,99% | [EINECS(EC#)]
220-355-7 | [Molecular Formula]
C8H11NO2 | [MDL Number]
MFCD00008371 | [Molecular Weight]
153.18 | [MOL File]
2735-04-8.mol |
| Chemical Properties | Back Directory | [Appearance]
black crystals | [Melting point ]
33-36 °C (lit.) | [Boiling point ]
75-80 C | [density ]
1.075 g/mL at 25 °C(lit.)
| [refractive index ]
1.4640 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Refrigerator | [form ]
Crystalline Solid | [pka]
5.14±0.10(Predicted) | [color ]
Dark brown | [Stability:]
Stability Stable, but sensitive to prolonged exposure to light. Incompatible with acids. | [Water Solubility ]
7 g/L (20 ºC) | [Detection Methods]
GC,NMR | [BRN ]
638704 | [InChI]
1S/C8H11NO2/c1-10-6-3-4-7(9)8(5-6)11-2/h3-5H,9H2,1-2H3 | [InChIKey]
GEQNZVKIDIPGCO-UHFFFAOYSA-N | [SMILES]
COc1ccc(N)c(OC)c1 | [CAS DataBase Reference]
2735-04-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenamine, 2,4-dimethoxy-(2735-04-8) | [Storage Precautions]
Store under nitrogen;Air sensitive;Light sensitive | [EPA Substance Registry System]
2735-04-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S22:Do not breathe dust . | [RIDADR ]
2811 | [WGK Germany ]
3
| [RTECS ]
BX4200000
| [F ]
8-10-23 | [TSCA ]
Yes | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29214200 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Hazardous Substances Data]
2735-04-8(Hazardous Substances Data) | [Toxicity]
mouse,LD50,oral,1gm/kg (1000mg/kg),Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to the National Cancer Institute by Litton Bionetics, Inc. Vol. NCI-E-C-72-3252, Pg. 1973, |
| Hazard Information | Back Directory | [General Description]
Black crystalline solid. | [Reactivity Profile]
2,4-DIMETHOXYANILINE(2735-04-8) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | [Air & Water Reactions]
Insoluble in water. | [Health Hazard]
ACUTE/CHRONIC HAZARDS: This compound is a local irritant. | [Chemical Properties]
black crystals | [Uses]
Various 2,4-dimethoxyphenylsemicarbazones were synthesized starting from 2,4-dimethoxyaniline via a phenylcarbamate intermediate. The hydrochloride of 2,4-dimethoxyaniline was prepared by intro- ducing hydrogen chloride gas into an etheral solution and washing the precipitate with absolute diethyl ether. | [Synthesis Reference(s)]
Tetrahedron Letters, 34, p. 2441, 1993 DOI: 10.1016/S0040-4039(00)60436-7 |
|
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