ChemicalBook--->CAS DataBase List--->28240-69-9

28240-69-9

28240-69-9 Structure

28240-69-9 Structure
IdentificationMore
[Name]

1,2-BIS(DICHLOROPHOSPHINO)ETHANE
[CAS]

28240-69-9
[Synonyms]

1,2-BIS(DICHLOROPHOSPHINO)ETHANE
1,2-Bis(dichlorophosphino)ethane,min.97%
1,2-BIS(DICHLOROPHOSPHINO)ETHANE, MIN. 97%
1,2-Bis(dichlorophosphino)ethane, 97+%
Ethylenebis(dichlorophosphine)
[Molecular Formula]

C2H4Cl4P2
[MDL Number]

MFCD00009609
[Molecular Weight]

231.81
[MOL File]

28240-69-9.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Boiling point ]

70 °C1 mm Hg(lit.)
[density ]

1.536 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.588(lit.)
[Fp ]

70°C/1mm
[form ]

liquid
[color ]

colorless to pale yellow
[Sensitive ]

Moisture Sensitive
[InChI]

1S/C2H4Cl4P2/c3-7(4)1-2-8(5)6/h1-2H2
[InChIKey]

SBWAJHLQMFBNIN-UHFFFAOYSA-N
[SMILES]

ClP(Cl)CCP(Cl)Cl
[CAS DataBase Reference]

28240-69-9(CAS DataBase Reference)
[EPA Substance Registry System]

Phosphonous dichloride, 1,2-ethanediylbis- (28240-69-9)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29310099
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Skin Corr. 1B
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

1,2-Bis(dichlorophosphino)ethane can be used as a precursor to synthesize ethylenebis(phosphonic dichloride).
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
[Synthesis]

The synthetic route to 1,2-bis(dichlorophosphoryl)-ethane involves palladium-catalyzed reactions, ligand chemistry, and diphosphine ligands. It is synthesized from ethane in two steps: first, it is chlorinated by reaction with PdCl(CHCl) to form chloroeth
Spectrum DetailBack Directory
[Spectrum Detail]

1,2-BIS(DICHLOROPHOSPHINO)ETHANE(28240-69-9)1HNMR
1,2-BIS(DICHLOROPHOSPHINO)ETHANE(28240-69-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,2-Bis(dichlorophosphino)ethane, 97%(28240-69-9)
[Alfa Aesar]

1,2-Bis(dichlorophosphino)ethane, 97+%(28240-69-9)
[Sigma Aldrich]

28240-69-9(sigmaaldrich)
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