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28697-53-2

28697-53-2 Structure

28697-53-2 Structure
IdentificationMore
[Name]

D(-)-Arabinose
[CAS]

28697-53-2
[Synonyms]

(3S,4R,5R)-OXANE-2,3,4,5-TETROL
D-ARA
D-(-)-ARABINOSE
D-ARABINOSE
D(-)-ARABINOSE MOLECULAR BIOLOGYREAGENT
D-(-)-ARABINOSE SIGMAULTRA
D-Arabinopyranose (9CI)
biotechgrade
D(-)-Arabinose, 99+%
D-Arabinopyranose
D(-)-Arabinose
D-Arabinose
D-ARABINOSE extrapure
[EINECS(EC#)]

233-708-5
[Molecular Formula]

C5H10O5
[MDL Number]

MFCD00064361
[Molecular Weight]

150.13
[MOL File]

28697-53-2.mol
Chemical PropertiesBack Directory
[Appearance]

White to off-white powder
[Melting point ]

162-164 °C(lit.)
[alpha ]

-103.5 º (c=4, H2O, 24hrs.)
[Boiling point ]

191.65°C (rough estimate)
[density ]

1.1897 (rough estimate)
[refractive index ]

1.3920 (estimate)
[storage temp. ]

Store at RT.
[solubility ]

H2O: 1 M at 20 °C, clear, colorless
[form ]

Liquid
[pka]

12.26±0.70(Predicted)
[color ]

Clear
[Water Solubility ]

soluble
[Stability:]

Hygroscopic
[InChI]

InChI=1S/C5H10O5/c6-2-1-10-5(9)4(8)3(2)7/h2-9H,1H2/t2-,3-,4+,5?/m1/s1
[InChIKey]

SRBFZHDQGSBBOR-ZRMNMSDTSA-N
[SMILES]

OC1OC[C@@H](O)[C@@H](O)[C@@H]1O
[CAS DataBase Reference]

28697-53-2(CAS DataBase Reference)
Safety DataBack Directory
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

3-10
[HS Code ]

29400090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrogen peroxide-->Calcium gluconate
[Preparation Products]

D-(-)-Arabinose-->D-ARABINO-1,4-LACTONE
Hazard InformationBack Directory
[Chemical Properties]

White to off-white powder
[Uses]

An inhibitor of the enzyme glucose dehydrogenase.
[Definition]

ChEBI: D-arabinopyranose is d-Arabinose in its pyranose form.
[storage]

Store at RT
[Purification Methods]

Crystallise D-(-)-arabinose three times from EtOH, dry it in vacuo at 60o for 24hours and store it in a vacuum desiccator. It also crystallises from a mixture of H2O/MeOH/EtOH with m 158-160o, or H2O with m 160-161o. [Whistler & Schweiger J Am Chem Soc 81 5190 1959, Fletcher et al. J Am Chem Soc 72 4546 1950, Beilstein 1 IV 4215, see Angyal Adv Carbohydrate Chem Biochem 42 15 1984 for ratio of anomers in solution.]
Spectrum DetailBack Directory
[Spectrum Detail]

D-Arabinpyranose(28697-53-2)1HNMR
D-Arabinpyranose(28697-53-2)13CNMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

D(-)-Arabinose, 99+%(28697-53-2)
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