| Identification | More | [Name]
N-METHYLANILINIUM TRIFLUOROACETATE | [CAS]
29885-95-8 | [Synonyms]
N-MATFA
N-METHYLANILINE TRIFLUOROACETATE
N-METHYLANILINIUM TRIFLUOROACETATE
TAMA
TRIFLUOROACETIC ACID N-METHYLANILINE SALT
TRIFLUOROACETIC ACID N-METHYLANILINIUM SALT
N-Methylaniline trifluoroacetate salt
N-Methylaniliniumtrifluoroacetate,99%
TAMA, Trifluoroacetic acid N-methylaniline salt | [EINECS(EC#)]
249-927-4 | [Molecular Formula]
C9H10F3NO2 | [MDL Number]
MFCD00043278 | [Molecular Weight]
221.18 | [MOL File]
29885-95-8.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO VERY SLIGHTLY GREYISH CRYSTALLINE NEEDLES | [Melting point ]
65-66 °C (lit.) | [density ]
1.2770 (estimate) | [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Solid | [color ]
Grey to Dark Grey | [Sensitive ]
Hygroscopic | [BRN ]
3638133 | [InChI]
1S/C7H9N.C2HF3O2/c1-8-7-5-3-2-4-6-7;3-2(4,5)1(6)7/h2-6,8H,1H3;(H,6,7) | [InChIKey]
TXXJGCVOHDSYBC-UHFFFAOYSA-N | [SMILES]
OC(=O)C(F)(F)F.CNc1ccccc1 | [CAS DataBase Reference]
29885-95-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [F ]
1-9 | [HS Code ]
2921.42.9000 | [HazardClass ]
9 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO VERY SLIGHTLY GREYISH CRYSTALLINE NEEDLES | [Uses]
N-?Methylaniline Trifluoroacetate is regent used in organic synthesis, functioning as an α-methylating agent for ketones and activates internucleodecoupling upon removal. | [Synthesis]
N-Methylanilinium Trifluoroacetate is prepared from commercial grade Trifluoroacetic Acid and N-methylaniline (1:1) in dry Et2O under a nitrogen atmosphere with cooling in an ice-bath. | [storage]
nonhygroscopic; not deliquescent; can be weighed in the air and stored
for months under an inert atmosphere. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Maya High Purity Chemicals
|
| Telephone: |
+86 (573) 82222445 (0)18006601000 452520369 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|