| Identification | Back Directory | [Name]
(DIMETHYLSULFIDE)GOLD(I) CHLORIDE | [CAS]
29892-37-3 | [Synonyms]
AuClS(Me)2
Chloro(methyl sulfide)gold
Chloro(dimethyl sulfide)gold
Dimethylsulfide gold chloride
CHLORO(DIMETHYLSULFIDE)GOLD(I)
(DiMethylsulfide)gole(I)chloride
(DIMETHYLSULFIDE)GOLD(I) CHLORIDE
(Dimethylsulfide)gole(I)chloride,95%
(Dimethylsulfide)gold(I) chloride,95%
Chloro(dimethylsulfide)gold(I), min. 97%
(DiMethylsulfide)gole(I)chloride, (CH3SCH3)AuCl | [Molecular Formula]
C2H6AuClS | [MDL Number]
MFCD00192090 | [MOL File]
29892-37-3.mol | [Molecular Weight]
294.55 |
| Chemical Properties | Back Directory | [Melting point ]
160°C(dec.)(lit.) | [storage temp. ]
0-10°C | [form ]
solid | [color ]
white to off-white | [Sensitive ]
light sensitive, store cold | [InChI]
InChI=1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H | [InChIKey]
PXVFOWATODEOKQ-UHFFFAOYSA-N | [SMILES]
S(C)(C)[Au+][Cl-] |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
3
| [HS Code ]
2930.90.9250 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
- chloro(trimesitylphosphine)gold(I)
- gold(I) N-heterocyclic carbene (NHC) complexes
- bis(carbene)gold(I) complex of ferrocenyl complexes
- gold(I) acetylide complexes
| [reaction suitability]
core: gold
reagent type: catalyst |
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