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29892-37-3

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29892-37-3 Structure

29892-37-3 Structure
IdentificationBack Directory
[Name]

(DIMETHYLSULFIDE)GOLD(I) CHLORIDE
[CAS]

29892-37-3
[Synonyms]

AuClS(Me)2
Chloro(methyl sulfide)gold
Chloro(dimethyl sulfide)gold
Dimethylsulfide gold chloride
CHLORO(DIMETHYLSULFIDE)GOLD(I)
(DiMethylsulfide)gole(I)chloride
(DIMETHYLSULFIDE)GOLD(I) CHLORIDE
(Dimethylsulfide)gole(I)chloride,95%
(Dimethylsulfide)gold(I) chloride,95%
Chloro(dimethylsulfide)gold(I), min. 97%
(DiMethylsulfide)gole(I)chloride, (CH3SCH3)AuCl
[Molecular Formula]

C2H6AuClS
[MDL Number]

MFCD00192090
[MOL File]

29892-37-3.mol
[Molecular Weight]

294.55
Chemical PropertiesBack Directory
[Melting point ]

160°C(dec.)(lit.)
[storage temp. ]

0-10°C
[form ]

solid
[color ]

white to off-white
[Sensitive ]

light sensitive, store cold
[InChI]

InChI=1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H
[InChIKey]

PXVFOWATODEOKQ-UHFFFAOYSA-N
[SMILES]

S(C)(C)[Au+][Cl-]
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[HS Code ]

2930.90.9250
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Reaction]

  1. Gold(I) precursor to more advanced gold catalysts
  2. Gold catalyst for the conversion of propargyl sulfoxides to α-thioenones.
Reactions of 29892-37-3
Hazard InformationBack Directory
[Uses]

Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
  • chloro(trimesitylphosphine)gold(I)
  • gold(I) N-heterocyclic carbene (NHC) complexes
  • bis(carbene)gold(I) complex of ferrocenyl complexes
  • gold(I) acetylide complexes

[reaction suitability]

core: gold
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

(DIMETHYLSULFIDE)GOLD(I) CHLORIDE(29892-37-3)1HNMR
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