| Identification | More | [Name]
N-[3-(TRIMETHOXYSILYL)PROPYL]ANILINE | [CAS]
3068-76-6 | [Synonyms]
(3-ANILINOPROPYL)TRIMETHOXYSILANE
3-(PHENYLAMINO)PROPYLTRIMETHOXYSILANE
N-[3-(TRIMETHOXYSILYL)PROPYL]ANILINE
N-PHENYL-3-AMINOPROPYLTRIMETHOXYSILANE
N-PHENYLAMINOPROPYLTRIMETHOXYSILANE
TRIMETHOXY[3-(PHENYLAMINO)PROPYL]SILANE
ZERENEX ZX007472
N-[.gamma.-(Trimethoxysilyl)propyl]aniline
n-[3-(trimethoxysilyl)propyl]-benzenamin
N-[3-(trimethoxysilyl)propyl]-Benzenamine
N-Phenyl-Gamma-Aminopropyltrim
Benzenamine, N-3-(trimethoxysilyl)propyl-
Phenylaminopropyltrimethoxysilane
(3-Anilinopropyl)trimethoxysilane, N-[3-(Trimethoxysilyl)propyl]aniline, [3-(Phenylamino)propyl]trimethoxysilane, Trimethoxy[3-(phenylamino)propyl]silane
(3-Anilinopropyl)trimethoxysilane, N-[3-(Trimethoxysilyl)propyl]aniline, [3-(Phenylamino)propyl]trimethoxysilane
N-Phenyl-3-(trimethoxysilyl)propane-1-amine
SZ-6083
Y-9669 | [EINECS(EC#)]
221-328-2 | [Molecular Formula]
C12H21NO3Si | [MDL Number]
MFCD00053673 | [Molecular Weight]
255.39 | [MOL File]
3068-76-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Yellowish clear liquid | [Melting point ]
<0°C | [Boiling point ]
310 °C(lit.) | [density ]
1.07 g/mL at 25 °C(lit.)
| [vapor pressure ]
0-0.042Pa at 25℃ | [refractive index ]
n20/D 1.506(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
2-8°C, protect from light | [form ]
liquid | [pka]
5.02±0.50(Predicted) | [color ]
Colorless to Light yellow to Light orange | [Specific Gravity]
1.07 | [Water Solubility ]
993-1000000mg/L at 20℃ | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [BRN ]
8620045 | [InChI]
1S/C12H21NO3Si/c1-14-17(15-2,16-3)11-7-10-13-12-8-5-4-6-9-12/h4-6,8-9,13H,7,10-11H2,1-3H3 | [InChIKey]
KBJFYLLAMSZSOG-UHFFFAOYSA-N | [SMILES]
CO[Si](CCCNc1ccccc1)(OC)OC | [LogP]
-0.6-2.5 | [CAS DataBase Reference]
3068-76-6(CAS DataBase Reference) | [EPA Substance Registry System]
3068-76-6(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
  
GHS05,GHS07,GHS08 | [Signal word ]
Danger | [Hazard statements ]
H314-H317-H341-H351-H372-H412 | [Precautionary statements ]
P202-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R40:Limited evidence of a carcinogenic effect.
R48/20/21/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3267 8/PG 2
| [WGK Germany ]
1
| [TSCA ]
Yes | [REACH Registrations]
Inactive | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29319090 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Aquatic Chronic 3
Carc. 2
Eye Dam. 1
Muta. 2
Skin Corr. 1B
Skin Sens. 1
STOT RE 1 |
| Hazard Information | Back Directory | [Chemical Properties]
Yellowish clear liquid | [Uses]
TMSPA is a monomer which can be polymerized to form poly(TMPSA). Poly(TMPSA) can be used to coat gold nanorods (AuNRs) to fabricate an electrode for the sensing of hydrogen peroxide. | [General Description]
N-(3-(Trimethoxysilyl)propyl)aniline (TMSPA) is an organoalkoxysilane derivative of polyaniline (PAN). TMSPA is a pH sensitive silica-polyaniline hybrid which is electroactive and electrochromic in nature. It is used as a silane coupling agent. | [Synthesis]
General procedure for the synthesis of N-phenyl-3-aminopropyltrimethoxysilane from aniline and 3-chloropropyltrimethoxysilane: 186 g of aniline and 182 g of polyaniline were added to the reactor. Subsequently, 198.7 g of 3-chloropropyltrimethoxysilane was added slowly and continuously dropwise to the reactor. During the reaction, the reaction temperature was maintained at 160 °C and the reaction was continuously stirred for 2 hours. After completion of the reaction, the reaction conditions were continued for 3 hours to ensure complete reaction. At the end of the reaction, the reaction mixture was separated by filtration to afford 229.8 g of N-phenyl-3-aminopropyltrimethoxysilane in 90.1% yield and 94.2% selectivity. Subsequently, the solid phase product was neutralized with ammonia and washed repeatedly with deionized water until the pH of the filtrate reached 6-7. Finally, the product was dried under vacuum at 80 °C to ensure that the moisture content did not exceed 1%. The dried product can be recycled as an acid scavenger. | [References]
[1] Patent: CN105481890, 2016, A. Location in patent: Paragraph 0015
[2] Doklady Chemistry, 2000, vol. 375, # 1-3, p. 250 - 252 |
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